Browsing by Subject "Analytical results"

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Open Access
Fluorescent Si QD decoration onto a flexible polymeric electrospun nanofibrous mat for the colorimetric sensing of TNT
(Royal Society of Chemistry, 2017) Arslan, O.; Aytac Z.; Uyar, Tamer
UV range light was used for the facile, effective and large-scale synthesis of visible light emitting, surface-protected silicon quantum dots (Si QDs) starting from an amine-functionalized alkoxy silane precursor. Within mild and easy hydrolysis/condensation environments, the use of an amine-functionalized precursor together with a reducing agent resulted in a bright visible green light that could be used for fluorescent analytical detection systems. Visible light emitting Si QDs were investigated and it was found that their emission character depends on the illumination time, hydrolysis/condensation conditions and pretreatments for the silane coupling agents. A Nylon 6,6 electrospun nanofibrous mat was selected as a substrate for decoration by the Si QDs in order to fabricate a flexible and free-standing polymeric nanofibrous mat posessing a visible light emitting character so that it could act as a visible colorimetric sensor. The visible light emitting Si QDs were decorated onto the Nylon 6,6 nanofibrous mats via covering the surfaces as a ‘nanodress’ by a simple impregnation/dip-coating and heat-curing methods. The analytical results revealed that the Si QDs decorated flexible polymeric nanofibrous mats could be utilized for colorimetric trinitrotoluene (TNT) detection in low concentrations.
Open Access
Two-dimensional complex parity-time-symmetric photonic structures
(American Physical Society, 2015-02) Turduev, M.; Botey, M.; Giden, I.; Herrero, R.; Kurt, H.; Özbay, Ekmel; Staliunas, K.
We propose a simple realistic two-dimensional complex parity-time-symmetric photonic structure that is described by a non-Hermitian potential but possesses real-valued eigenvalues. The concept is developed from basic physical considerations to provide asymmetric coupling between harmonic wave components of the electromagnetic field. The structure results in a nonreciprocal chirality and asymmetric transmission between in- and out-coupling channels into the structure. The analytical results are supported by a numerical study of the Bloch-like mode formations and calculations of a realistic planar semiconductor structure. © 2015 American Physical Society.