Browsing by Subject "Alloying"

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    Blue-emitting CdSe nanoplatelets enabled by sulfur-alloyed heterostructures for light-emitting diodes with low turn-on voltage
    (American Chemical Society, 2021-12-28) İzmir, M.; Sharma, A.; Shendre, S.; Durmuşoğlu, E. G.; Sharma, V. K.; Shabani, Farzan; Baruj, Hamed Dehghanpour; Delikanlı, Savaş; Sharma, M.; Demir, Hilmi Volkan
    Colloidal nanoplatelets (NPLs) have emerged as the last class of semiconductor nanocrystals for their potential optoelectronic applications. The heterostructures of these nanocrystals can achieve high photoluminescence quantum yield and enhanced photostability, along with color purity. Such advantages make them a promising candidate for solution-processable light-emitting diodes (LEDs). However, to date, blue-emitting CdSe nanoplatelets (NPLs) exhibit poor photoluminescence quantum yield and also typically suffer from a rolled-up morphology. To mitigate these problems in this work, we propose and demonstrate efficient alloyed 4 ML CdSe1–xSx nanoplatelets having a CdS crown with enhanced photoluminescence quantum yields (up to 60%) in the blue region (462–487 nm). We successfully used these NPLs as an electrically driven active emitter in the blue-emitting NPL-LEDs with a low turn-on voltage of ∼4 V. The Commission Internationale de L’Eclairage (CIE) coordinates of (0.23, 0.14) were obtained for these blue-emitting NPL-LEDs. These emitters could potentially open up the opportunity for full-color displays using these NPL-based blue LEDs in conjunction with the red and green ones.
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    ItemOpen Access
    Microstructural association between mechanical behavior with bending fracture surfaces in Astaloy CrA sintered parts alloyed by Cu and C
    (Elsevier Ltd, 2014) Khorsand H.; Ghaffari, M.; Ganjeh, E.
    Application of powder metallurgy technique, a method presenting both economic and technical concepts for producing sintered parts, has been expanding in automobile and other engineering industries. Powder metallurgy parts usually possess residual porosity in their microstructures deteriorating mechanical performance. There have been many solutions to increasing of strength in these parts such as applying different heat treatment or adding alloying elements. It is well known that Fe-Cu-C is the one of main alloying system for both increasing the strength and decreasing cost of them. In this study, the microstructure, mechanical properties (transverse rapture strength and hardness), crack behavior and fracture modes of a low alloy Fe-Cr powder (Astaloy CrA) with different amount of copper (0, 1 and 2. wt.%) and carbon, in form of graphite (0.45, 0.6 and 0.8. wt.%) sintered at conventional condition have been investigated. Microstructural evolution showed adding copper and graphite as alloying elements could generate widespread of strength (857-1380. MPa) and hardness (170-295 HV5). Developing different phases in microstructure was the main reason for various mechanical properties. Crack coalescence phenomenon leads to fracturing with ductile (at sinter-necks) and brittle morphology. Micro-mechanism of fracture related to transparticle and interparticle crack propagation. © 2013 Elsevier Ltd.
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    Understanding the suitable alloying conditions for highly efficient Cu- and Mn-doped Zn1-xCdxS/ZnS core-shell quantum dots
    (Elsevier B.V., 2023-10-20) Kaur, Manpreet; Sharma, Ashma; Erdem, Onur; Kumar, A.; Demir, Hilmi Volkan; Sharma, M.
    Doping of alloyed colloidal quantum dots (QDs) has garnered significant attention for providing tunable and Stokes-shifted emission. By alloying the host semiconductor nanocrystals (NCs), their band gap can be tuned. With the specific addition of dopant ions, these NCs can emit tunable emissions within the visible spectrum. However, while doped and alloyed quantum dots (QDs) have shown promise for tunable emissions, their emission qualities have not been consistent across the spectrum. Here, we report the synthesis of high-quality Cu- and Mn-doped ZnxCd1-xS (x = 0–1) alloyed QDs by a colloidal non-injection method. In this study, we examined the effect of different dopant ions on the optical properties of similar alloyed nanocrystals. The deposition of a ZnS shell on these doped QDs significantly improves their quantum yield (QY), increasing it from 7.0 % to 50.0 % for Cu-doped QDs and from 30.0 % to 80.0 % for Mn-doped QDs. The Cu-doped QDs exhibit tunable emission from green to red across the visible spectrum by varying the Zn/Cd ratio, whereas the Mn-doped QDs show a fixed orange emission. Interestingly, the Cu-doped alloyed QDs show a contrasting trend in quantum yield (QY) compared to those of Mn-doped QDs when the amount of Cd in ZnCdS alloyed QDs is systematically changed. As the amount of Cd increases in the ZnCdS alloyed QDs, the Cu-doped QDs show both an increase in average lifetime and an increase in QY. In contrast, for the Mn-doped QDs, the decay lifetime values remain fairly constant for different amounts of Cd in the ZnCdS alloyed QDs, but the QY decreases as the amount of Cd increases. The results of this study may facilitate the design of optimal alloying combinations for Cu/Mn-doped QDs in optoelectronic applications. © 2023 The Authors