Browsing by Subject "Ag nanoparticle"

Now showing 1 - 4 of 4

Open Access
Newly designed silver coated-magnetic, monodisperse polymeric microbeads as SERS substrate for low-level detection of amoxicillin
(Elsevier, 2016-09) Kibar, G.; Topal, A. E.; Dana, A.; Tuncel, A.
We report the preparation of silver-coated magnetic polymethacrylate core-shell nanoparticles for use in surface-enhanced Raman scattering based drug detection. Monodisperse porous poly (mono-2-(methacryloyloxy)ethyl succinate-co-glycerol dimethacrylate), poly (MMES-co-GDMA) microbeads of ca. 5 μm diameter were first synthesized through a multistage microsuspension polymerization technique to serve as a carboxyl-bearing core region. Microspheres were subsequently magnetized by the co-precipitation of ferric ions, aminated through the surface hydroxyl groups and decorated with Au nanoparticles via electrostatic attraction. An Ag shell was then formed on top of the Au layer through a seed-mediated growth process, resulting in micron-sized monodisperse microbeads that exhibit Raman enhancement effects due to the roughness of the Ag surface layer. The core-shell microspheres were used as a new substrate for the detection of amoxicillin at trace concentrations up to 10-8 M by SERS. The proposed SERS platform can be evaluated as a useful tool for the follow-up amoxicillin pollution and low-level detection of amoxicillin in aqueous media.
Open Access
A plasmonic enhanced photodetector based on silicon nanocrystals obtained through laser ablation
(Institute of Physics Publishing, 2012-10-18) Alkis, S.; Oruç, F. B.; Ortaç, B.; Koşger, A. C.; Okyay, Ali Kemal
We present a proof-of-concept photodetector which is sensitive in the visible spectrum. Silicon nanocrystals (Si-NCs) obtained by laser ablation are used as the active absorption region. Si-NC films are formed from a polymeric dispersion. The films are sandwiched between thin insulating films to reduce the electrical leakage current. Furthermore, Ag nanoparticles are integrated with the photodetector to enhance the visible response using plasmonic effects. The measured photocurrent is resonantly enhanced, which is explained in terms of enhanced local fields caused by localized plasmons. The UV-vis spectrum of Ag nanoparticles is also measured to verify the resonance.
Open Access
Terahertz time-domain study of silver nanoparticles synthesized by laser ablation in organic liquid
(IEEE Microwave Theory and Techniques Society, 2016-07) Koral, C.; Ortaç, B.; Altan, H.
We report the investigation of laser-synthesized Ag nanoparticles (Ag-NPs) in an organic liquid environment by using terahertz time-domain spectroscopy (THz-TDS) technique. Colloidal Ag-NPs with an average diameter of 10 nm in two-propanol solution through nanosecond pulsed laser ablation were synthesized. THz-TDS measurements were performed on different volumetric concentration of Ag-NPs suspensions placed in 2-mm path length quartz cuvette. Due to the dispersive and highly absorptive nature of the nano liquids, an approach based on extracting the optical properties through the changes in amplitude and phase solely around the main peak of THz waveform is developed. This approach allowed for an accurate estimation of the complex refractive index of the Metallic-NPs suspension for the different prepared volumetric concentrations. In addition, using Maxwell-Garnett theory, the NP concentration is also extracted. This method shows that the time-domain nature of the THz pulse measurement technique is extremely useful in instances where slight variations in highly dispersive samples need to be investigated.
Open Access
Understanding the plasmonic properties of dewetting formed Ag nanoparticles for large area solar cell applications
(Optical Society of American (OSA), 2013) Günendi, M.C.; Tanyeli I.; Akgüç G.B.; Bek, A.; Turan, R.; Gülseren O.
The effects of substrates with technological interest for solar cell industry are examined on the plasmonic properties of Ag nanoparticles fabricated by dewetting technique. Both surface matching (boundary element) and propagator (finite difference time domain) methods are used in numerical simulations to describe plasmonic properties and to interpret experimental data. The uncertainty on the locations of nanoparticles by the substrate in experiment is explained by the simulations of various Ag nanoparticle configurations. The change in plasmon resonance due to the location of nanoparticles with respect to the substrate, interactions among them, their shapes, and sizes as well as dielectric properties of substrate are discussed theoretically and implications of these for the experiment are deliberated. ©2013 Optical Society of America.