Browsing by Subject "Ablation"

Now showing 1 - 12 of 12

Open Access
Ablation-cooled material removal at high speed with femtosecond pulse bursts
(OSA, 2015) Kerse, Can; Kalaycıoğlu, Hamit; Elahi, Parviz; Akçaalan, Önder; Yavaş, S.; Aşık, M. D.; Kesim, Deniz Koray; Yavuz, Koray; Çetin, Barbaros; İlday, Fatih Ömer
We report exploitation of ablation cooling, a concept well-known in rocket design, to remove materials, including metals, silicon, hard and soft tissue. Exciting possibilities include ablation using sub-microjoule pulses with efficiencies of 100-mJ pulses.
Open Access
Fluence of thulium laser system in skin ablation
(IEEE, 2010) Bilici, T.; Tabakoğlu, O.; Kalaycıoğlu, Hamit; Kurt, A.; Sennaroglu, A.; Gülsoy, M.
Tm:YAP laser system at power levels up to 1.2 W at 1980 nm was established in both continuous-wave and modulated modes of operation. The fluence effect of the laser system for skin ablation was analyzed by histology analysis with Wistar rat skin tissues. Thermally altered length, thermally altered area, ablation area, and ablation depth parameters were measured on histology images of skin samples just after the laser operation and after four-day healing period. Continuous-wave mode of operation provided higher thermal effects on the skin samples. Lower fluence levels were found for efficient ablation effect. © 2010 IEEE.
Open Access
Generation of picosecond pulses directly from a 100 W, burst-mode, doping-managed Yb-doped fiber amplifier
(Optical Society of America, 2014) Elahi, P.; Yilmaz, S.; Eldeniz, Y. B.; Ilday, F. O.
Burst-mode laser systems offer increased effectiveness in material processing while requiring lower individual pulse energies. Fiber amplifiers operating in this regime generate low powers in the order of 1 W. We present a Yb-doped fiber amplifier, utilizing doping management, that scales the average power up to 100 W. The laser system produces bursts at 1 MHz, where each burst comprises 10 pulses with 10 mu J energy per pulse and is separated in time by 10 ns. The high-burst repetition rate allows substantial simplification of the setup over previous demonstrations of burst-mode operation in fiber lasers. The total energy in each burst is 100 mu J and the average power achieved within the burst is 1 kW. The pulse evolution in the final stage of amplification is initiated as self-similar amplification, which is quickly altered as the pulse spectrum exceeds the gain bandwidth. By prechirping the pulses launched into the amplifier, 17 ps long pulses are generated without using external pulse compression. The peak power of the pulses is similar to 0.6 MW. (C) 2014 Optical Society of America
Open Access
Generation of ultra-small InN nanocrystals by pulsed laser ablation of suspension in organic solution
(Springer Verlag, 2017-03) Kurşungöz, C.; U. Şimşek, E.; Tuzaklı, R.; Ortaç, B.
Nanostructures of InN have been extensively investigated since nano-size provides a number of advantages allowing applications in nanoscale electronic and optoelectronic devices. It is quite important to obtain pure InN nanocrystals (InN-NCs) to reveal the characteristic features, which gain interest in the literature. Here, we proposed a new approach for the synthesis of ultra-small hexagonal InN-NCs by using suspension of micron-sized InN powder in ethanol with pulsed laser ablation method. The liquid environment, laser energy and ablation time were optimized and a post-synthesis treatment, centrifugation, was performed to achieve InN-NCs with the smallest size. Besides, the micron-sized InN powder suspension, as a starting material, enabled us to obtain InN-NCs having diameters smaller than 5 nm. We also presented a detailed characterization of InN-NCs and demonstrated that the formation mechanism mainly depends on the fragmentation due to laser irradiation of the suspension.
Open Access
High-speed, thermal damage-free ablation of brain tissue with femtosecond pulse bursts
(IEEE, 2016) Kerse, Can; Yavaş, Seydi; Kalaycıoğlu, Hamit; Asik M.D.; Akçaalan, Önder; İlday, F. Ömer
We report a novel ultrafast burst mode fiber laser system and results on ablation of rat brain tissue at rates approaching an order of magnitude improvement over previous reports, with no discernible thermal damage. © 2015 IEEE.
Open Access
Nanosecond pulsed laser ablated sub-10 nm silicon nanoparticles for improving photovoltaic conversion efficiency of commercial solar cells
(Institute of Physics Publishing Ltd., 2017) Rasouli, H. R.; Ghobadi, A.; Ghobadi, T. G. U.; Ates, H.; Topalli, K.; Okyay, Ali Kemal
In this paper, we demonstrate the enhancement of photovoltaic (PV) solar cell efficiency using luminescent silicon nanoparticles (Si-NPs). Sub-10 nm Si-NPs are synthesized via pulsed laser ablation technique. These ultra-small Si nanoparticles exhibit photoluminescence (PL) character tics at 425 and 517 nm upon excitation by ultra-violet (UV) light. Therefore, they can act as secondary light sources that convert high energetic photons to ones at visible range. This down-shifting property can be a promising approach to enhance PV performance of the solar cell, regardless of its type. As proof-of-concept, polycrystalline commercial solar cells with an efficiency of ca 10% are coated with these luminescent Si-NPs. The nanoparticle-decorated solar cells exhibit up to 1.64% increase in the external quantum efficiency with respect to the uncoated reference cells. According to spectral photo-responsivity characterizations, the efficiency enhancement is stronger in wavelengths below 550 nm. As expected, this is attributed to down-shifting via Si-NPs, which is verified by their PL characteristics. The results presented here can serve as a beacon for future performance enhanced devices in a wide range of applications based on Si-NPs including PVs and LED applications.
Open Access
Novel one-step synthesis of silica nanoparticles from sugarbeet bagasse by laser ablation and their effects on the growth of freshwater algae culture
(Elsevier, 2014) San, N. O.; Kurşungöz, C.; Tümtaş, Y.; Yaşa, Ö.; Ortac, B.; Tekinay, T.
Scientific research involving nanotechnology has grown exponentially and has led to the development of engineered nanoparticles (NPs). Silica NPs have been used in numerous scientific and technological applications over the past decade, necessitating the development of efficient methods for their synthesis. Recent studies have explored the potential of laser ablation as a convenient way to prepare metal and oxide NPs. Due to its high silica content, low cost, and widespread availability, sugarbeet bagasse is highly suitable as a raw material for producing silica NPs via laser ablation. In this study, two different NP production methods were investigated: laser ablation and NaOH treatment. We developed a novel, one-step method to produce silica NPs from sugarbeet bagasse using laser ablation, and we characterized the silica NPs using environmental scanning electron microscopy (ESEM), energy dispersive spectrometry (EDS), dynamic light scattering (DLS), transmission electron microscopy (TEM), attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. EDS analysis and XPS confirmed the presence of silica NPs. The NPs produced by laser ablation were smaller (38-190 nm) than those produced by NaOH treatment (531-825 nm). Finally, we demonstrated positive effects of silica NPs produced from laser ablation on the growth of microalgae, and thus, our novel method may be beneficial as an environmentally friendly procedure to produce NPs.
Open Access
Rapid fabrication of microfluidic PDMS devices from reusable PDMS molds using laser ablation
(Institute of Physics Publishing, 2016) Isiksacan, Z.; Guler, M. T.; Aydogdu, B.; Bilican, I.; Elbuken, C.
The conventional fabrication methods for microfluidic devices require cleanroom processes that are costly and time-consuming. We present a novel, facile, and low-cost method for rapid fabrication of polydimethylsiloxane (PDMS) molds and devices. The method consists of three main fabrication steps: female mold (FM), male mold (MM), and chip fabrication. We use a CO2 laser cutter to pattern a thin, spin-coated PDMS layer for FM fabrication. We then obtain reusable PDMS MM from the FM using PDMS/PDMS casting. Finally, a second casting step is used to replicate PDMS devices from the MM. Demolding of one PDMS layer from another is carried out without any potentially hazardous chemical surface treatment. We have successfully demonstrated that this novel method allows fabrication of microfluidic molds and devices with precise dimensions (thickness, width, length) using a single material, PDMS, which is very common across microfluidic laboratories. The whole process, from idea to device testing, can be completed in 1.5 h in a standard laboratory.
Open Access
SSFP-based MR thermometry
(John Wiley & Sons, 2004) Paliwal, V.; El-Sharkawy, A.-M.; Du, X.; Yang, X.; Atalar, Ergin
Of the various techniques employed to quantify temperature changes by MR, proton resonance frequency (PRF) shift-based phase-difference imaging (PDI) is the most accurate and widely used. However, PDI is associated with various artifacts. Motivated by these limitations, we developed a new method to monitor temperature changes by MRI using the balanced steady-state free precession (balanced-SSFP) pulse sequence. Magnitude images obtained with the SSFP pulse sequence were used to find the PRF shift, which is proportional to temperature change. Spatiotemporal temperature maps were successfully reconstructed with this technique in gel phantom experiments and a rabbit model. The results show that the balanced-SSFP-based method is a promising new technique for monitoring temperature.
Open Access
Synthesis of blue-shifted luminescent colloidal GaN nanocrystals through femtosecond pulsed laser ablation in organic solution
(Springer Netherlands, 2016-05) Demirel, A.; Öztaş T.; Kurşungöz, C.; Yılmaz, İ.; Ortaç, B.
We demonstrate the synthesis of GaN nanocrystals (NCs) with the sizes of less than the doubled exciton Bohr radius leading quantum confinement effects via a single-step technique. The generation of colloidal GaN nanoparticles (NPs) in organic solution through nanosecond (ns) and femtosecond (fs) pulsed laser ablation (PLA) of GaN powder was carried out. Ns PLA in ethanol and polymer matrix resulted in amorphous GaN-NPs with the size distribution of 12.4 ± 7.0 and 6.4 ± 2.3 nm, respectively, whereas fs PLA in ethanol produced colloidal GaN-NCs with spherical shape within 4.2 ± 1.9 nm particle size distribution. XRD and selected area electron diffraction analysis of the product via fs PLA revealed that GaN-NCs are in wurtzite structure. Moreover, X-ray photoelectron spectroscopy measurements also confirm the presence of GaN nanomaterials. The colloidal GaN-NCs solution exhibits strong blue shift in the absorption spectrum compared to that of the GaN-NPs via ns PLA in ethanol. Furthermore, the photoluminescence emission behavior of fs PLA-generated GaN-NCs in the 295–400 nm wavelength range is observed with a peak position located at 305 nm showing a strong blue shift with respect to the bulk GaN.
Open Access
Synthesis of colloidal 2D / 3D MoS2 nanostructures by pulsed laser ablation in an organic liquid environment
(American Chemical Society, 2014) Oztas, T.; Sen, H. S.; Durgun, Engin; Ortaç, B.
Two-dimensional MoS2 nanosheets (2D MoS2 NS) and fullerene-like MoS2 nanostructures (3D MoS2 NS) with varying sizes are synthesized by nanosecond laser ablation of hexagonal crystalline 2H-MoS2 powder in organic solution (methanol). Structural, chemical, and optical properties of MoS2 NS are characterized by optical microscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and Raman and UV-vis-near infrared absorption spectroscopy techniques. Results of the structural analysis show that the obtained MoS2 NS mainly present a layered morphology from micrometer to nanometer sized surface area. Detailed analysis of the product also proves the existence of inorganic polyhedral fullerene-like 3D MoS2 NS generated by pulsed laser ablation in methanol. The possible factors which may lead to formation of both 2D and 3D MoS2 NS in methanol are examined by ab initio calculations and shown to correlate with vacancy formation. The hexagonal crystalline structure of MoS2 NS was determined by XRD analysis. In Raman spectroscopy, the peaks at 380.33 and 405.79 cm-1 corresponding to the E1 2g and A1g phonon modes of MoS2 were clearly observed. The colloidal MoS2 NS solution presents broadband absorption edge tailoring from the UV region to the NIR region. Investigations of MoS2 NS show that the one-step physical process of pulsed laser ablation-bulk MoS2 powder interaction in organic solution opens doors to the formation of two scaled micrometer- and nanometer-sized layered and fullerene-like morphology MoS2 structures. © 2014 American Chemical Society.
Open Access
Terahertz time-domain study of silver nanoparticles synthesized by laser ablation in organic liquid
(IEEE Microwave Theory and Techniques Society, 2016-07) Koral, C.; Ortaç, B.; Altan, H.
We report the investigation of laser-synthesized Ag nanoparticles (Ag-NPs) in an organic liquid environment by using terahertz time-domain spectroscopy (THz-TDS) technique. Colloidal Ag-NPs with an average diameter of 10 nm in two-propanol solution through nanosecond pulsed laser ablation were synthesized. THz-TDS measurements were performed on different volumetric concentration of Ag-NPs suspensions placed in 2-mm path length quartz cuvette. Due to the dispersive and highly absorptive nature of the nano liquids, an approach based on extracting the optical properties through the changes in amplitude and phase solely around the main peak of THz waveform is developed. This approach allowed for an accurate estimation of the complex refractive index of the Metallic-NPs suspension for the different prepared volumetric concentrations. In addition, using Maxwell-Garnett theory, the NP concentration is also extracted. This method shows that the time-domain nature of the THz pulse measurement technique is extremely useful in instances where slight variations in highly dispersive samples need to be investigated.