Browsing by Author "Yalçin, T."
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Item Open Access A conducting composite of polypyrrole I. synthesis and characterization(Elsevier, 1994-02) Selampinar, F.; Akbulut, U.; Yalçin, T.; Süzer, Ş.; Toppare, L.A conducting composite of polypyrrole was prepared via electrochemical methods. A polyamide was used as the insulating matrix polymer. The characterization of the composite was done by FT-IR, SEM, TGA, DSC and pyrolysis studies. Conductivity and solubility studies together with spectroscopic methods reveal that H bonding exists between the two polymers and a possible grafting to a certain extent.Item Open Access A conducting composite of polypyrrole II. As a gas sensor(Elsevier, 1995) Selampinar, F.; Toppare, L.; Akbulut, U.; Yalçin, T.; Süzer, Ş.Pure polypyrrole (PPy) and polypyrrole-polyamide (PPy-PA) composite films were synthesized electrochemically. The gas-sensing ability was investigated for both pure PPy and PPy-PA films. The composite films' response to several gases are better defined and reproducible compared to pristine conducting polymer. Electrochemical behaviour of PPy and PPy-PA electrodes in the presence of pyrrole and pyrrole-free medium is investigated via cyclic voltammetry. Mass spectrometry studies strictly reveal that the composite is completely different to a mechanical mixture. This phenomenon is discussed in comparison to polyaniline-polycarbonate composite. © 1995.