Browsing by Author "Kulik, Igor Orestovich"
Now showing 1 - 1 of 1
Results Per Page
Sort Options
Item Open Access Contraction of atomic orbitals in the oxygen anion network and superconductivity in metal oxide compounds(TÜBİTAK, 1996) Kulik, Igor OrestovichAnion network in the CuO2 plane of metal-oxide compound is considered as an intrinsic-hole metal with holes rather than electrons comprising a Fermi liquid immersed in the background of negative O2- ions. Due to the contraction of p-orbital of oxygen as a result of occupation by a hole, hole hopping between nearest neighbor sites (i, j) is dependent upon hole occupation as tij,σ = to + Vni,-σnj,-σ = W(ni,-σ + nj,-σ). Coupling parameters W and V (additive and multiplicative "contraction interaction" terms) result in the binding of holes into singlet, on-site configuration, or into triplet, nearest-neighbor-site configuration, due to W and V respectively. In the weak coupling limit, W results in the BCS type of superconductive pairing (singlet, s-wave), whereas multiplicative contraction V provides for either singlet, d-wave, or triplet, p-wave-like pairing states. It is concluded that the latter state may result in a plausible mechanism for high-Tc superconductivity in metal oxide compounds. The superconducting p-phase is shown to be in accord with recently published symmetry tests of the order parameter in oxides.