Browsing by Author "Aksoylu, A. E."

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Open Access
The effect of impregnation strategy on methane dry reforming activity of Ce promoted Pt/ZrO2
(Elsevier, 2009-12) Özkara-Aydınoğlu, Ş.; Özensoy, E.; Aksoylu, A. E.
Dry reforming of methane has been studied over Pt/ZrO2 catalysts promoted with Ce for different temperatures and feed compositions. The influence of the impregnation strategy and the cerium amount on the activity and stability of the catalysts were investigated. The results have shown that introduction of 1 wt.% Ce to the Pt/ZrO2 catalyst via coimpregnation method led to the highest catalytic activity and stability. 1 wt.%Ce-1 wt.%Pt/ZrO2 catalyst prepared by sequential impregnation displayed inferior CH4 and CO2 conversion performances with lowest H-2/CO production ratios. 1 wt.%Ce-1 wt.%Pt/ZrO2 catalyst prepared by coimpregnation showed the highest activity even for the feed with high CH4/CO2 ratio. The reason for high activity was explained by the intensive interaction between Pt and Ce phases for coimpregnated sample, which had been verified by X-ray photoelectron spectroscopy and Energy Dispersive X-Ray analyses. Strong and extensive Pt-Ce surface interaction results in an increase in the number of Ce3+ sites and enhances the dispersion of Pt.
Open Access
The effects of Co / Ce loading ratio and reaction conditions on CDRM performance of Co-Ce / ZrO2 catalysts
(Elsevier, 2018) Paksoy, A. İ.; Çağlayan, B. S.; Özensoy, Emrah; Ökte, A. N.; Aksoylu, A. E.
This work mainly aims to establish a link between Co/Ce loading ratio in Co-Ce/ZrO2 catalysts and their Carbon Dioxide Reforming of Methane (CDRM) performance. In this context, catalysts with different Co and Ce loadings were prepared and characterized via BET, XRD, HRTEM-EDX, XPS and Raman, and parametrically tested under different CDRM conditions. Dispersion of Co particles was nonhomogeneous on all samples. For the sample with the highest Co/Ce ratio (10%Co-2%Ce/ZrO2), higher amount of lattice oxygen vacancies and lowest degree of ceria reduction were determined. Raman analysis showed that graphitic carbon coexisted with amorphous carbon on the surface of all spent samples. The extent of side reactions prevailed in determining selectivity. It was expressed that both Co-Ce synergistic interaction and synchronous contribution of Ce and ZrO2 were enhanced for the samples having lower Co/Ce ratio. It was confirmed that Ce is only responsible for oxygen transfer but not its formation.
Open Access
Influence of La and Si promoters on the anaerobic heterogeneous catalytic decomposition of ammonium dinitramide (ADN) via alumina supported iridium active sites
(Elsevier, 2022-02-25) Kurt, Merve; Kap, Zeynep; Senol, Sinem; Ercan, Kerem Emre; Sika-Nartey, Abel Tetteh; Kocak, Yusuf; Koc, A.; Esiyok, H.; Caglayan, B. S.; Aksoylu, A. E.; Ozensoy, Emrah
Structural origins of the promotional effects of the La or Si doping of alumina supported Ir catalysts in anaerobic ammonium dinitramide decomposition were investigated. Our findings reveal that Ir/Al2O3 and Ir/La-Al2O3 favorably lower the onset temperature of the ADN decomposition reaction, whereas Si doping boosts the pressure generation during the reaction. Formation of mostly metallic Ir nanoparticles for Ir/Al2O3 and Ir/La-Al2O3 enables the lowering of the activation energy of the reaction. On the other hand, enhancement due to Si promotion is associated to the generation of small oxidic Irnx+ clusters which are strongly interacting with the SiOx-AlOx surface domains of the support material. Fundamental structure-functionality relationships unraveled in the current work may allow design of novel catalytic systems for aerospace monopropellant propulsion systems with higher performance by simultaneous exploitation of Ir active sites with different electronic properties.