In this study, the relation of the maximum ionization height (HmF2) and the critical frequency (FoF2) of F2 layer is examined within their parametric range through the International Reference Ionosphere extended towards the plasmasphere (IRI-Plas) model and the IONOLAB-TEC. HmF2 and FoF2 are optimized using an iterational loop through Non-Linear Least Squares method. HmF2 and FoF2 are obtained for various locations including Turkey for the same quiet day. Results are compared with ionosonde data where available. This study enables the modification and update of empirical and deterministic IRI Model to include instantaneous variability of the ionosphere. © 2011 IEEE.