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dc.contributor.authorUsanmaz, Ali
dc.date.accessioned2020-11-06T11:54:42Z
dc.date.available2020-11-06T11:54:42Z
dc.date.issued1997
dc.identifier.issn1300-0527
dc.identifier.urihttp://hdl.handle.net/11693/54436
dc.description.abstractCrystal structure of arcylamide at -150∘C was studied to understand the role of the crystal structure on the reaction mechanism of radiation-induced polymerization in the solid-state. Acrylamide crystallizes in the monoclinic unit cell with the unit cell parameters as ; a=828.0(2) pm, b=578.0(4) pm, c=974.9(2) pm, β=119.62(4)∘, space group =P 21/c, Z=4 molecules/unit cell, dx = 1.165 g/cm3. From the results of the structural data a polymerization mechanism in the solid-state is suggested. The radiation damage in single crystal of acrylamide was also investigated in detail. The result showed the formation of the amorphous polymer, that phase separated from the crystalline monomer. The post polymerization proceed at the interface of polymer-monomer up to 100% conversion.en_US
dc.language.isoEnglishen_US
dc.source.titleTurkish Journal of Chemistryen_US
dc.titleCrystal structure effect in radiation-induced solid-state polymerization of acrylamideen_US
dc.typeArticleen_US
dc.departmentDepartment of Chemistryen_US
dc.citation.spage304en_US
dc.citation.epage312en_US
dc.citation.volumeNumber21en_US
dc.citation.issueNumber4en_US
dc.publisherTÜBİTAKen_US
dc.contributor.bilkentauthorUsanmaz, Ali
dc.identifier.eissn1303-6130


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