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dc.contributor.authorKap, Zeynepen_US
dc.contributor.authorKaradaş, Ferdien_US
dc.date.accessioned2020-02-14T12:23:22Z
dc.date.available2020-02-14T12:23:22Z
dc.date.issued2019
dc.identifier.issn1359-6640
dc.identifier.urihttp://hdl.handle.net/11693/53369
dc.description.abstractA facile synthesis for a photosensitizer–water oxidation catalyst (PS–WOC) dyad, which is connected through a polymeric platform, has been reported. The dyad assembly consists of a ruthenium-based chromophore and a cobalt–iron pentacyanoferrate coordination network as the water oxidation catalyst while poly(4-vinylpyridine) serves as the bridging group between two collaborating units. Photocatalytic experiments in the presence of an electron scavenger reveal that the dyad assembly maintains its activity for 6 h while the activity of a cobalt hexacyanoferrate and Ru(bpy)32+ couple decreases gradually and eventually decays after a 3 h catalytic experiment. Infrared and XPS studies performed on the post-catalytic powder sample confirm the stability of the dyad during the catalytic process.en_US
dc.language.isoEnglishen_US
dc.source.titleFaraday Discussionsen_US
dc.relation.isversionofhttps://dx.doi.org/10.1039/c8fd00166aen_US
dc.titleVisible light-driven water oxidation with a ruthenium sensitizer and a cobalt-based catalyst connected with a polymeric platformen_US
dc.typeArticleen_US
dc.departmentDepartment of Chemistryen_US
dc.departmentInstitute of Materials Science and Nanotechnology (UNAM)en_US
dc.citation.spage111en_US
dc.citation.epage122en_US
dc.citation.volumeNumber215en_US
dc.identifier.doi10.1039/c8fd00166aen_US
dc.publisherRoyal Society of Chemistryen_US
dc.contributor.bilkentauthorKap, Zeynep
dc.contributor.bilkentauthorKaradaş, Ferdi
dc.identifier.eissn1364-5498


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