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      Supramolecular assemblies constructed by cucurbituril-catalyzed click reaction

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      Author(s)
      Tuncel, D.
      Ünal, Ö.
      Artar, M.
      Date
      2011
      Source Title
      Israel Journal of Chemistry
      Print ISSN
      0021-2148
      Electronic ISSN
      1869-5868
      Volume
      51
      Issue
      5-6
      Pages
      525 - 532
      Language
      English
      Type
      Article
      Item Usage Stats
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      Abstract
      Cucurbituril homologues are multi-functional macrocycles that can find applications in many areas and have numerous interesting features setting them apart from the other macrocycles. Among them, the ability of one of the cucurbituril homologues, cucurbit[6]uril (CB6), to catalyze 1,3- dipolar cycloaddition in a regiospecific fashion is truly exceptional. Using this feature, small molecules can be clicked together to form complex structures in a very efficient way. Accordingly, in this article we review recent research involving the use of CB6-catalyzed 1,3-dipolar cycloaddition or the click reaction of CB6 in the construction of supramolecular assemblies including rotaxanes, pseudorotaxanes, polyrotaxanes, polypseudorotaxanes, molecular switches, machines, and nanovalves.
      Keywords
      1,3-dipolar cycloaddition
      Click chemistry
      Cucurbiturils
      Rotaxanes
      Supramolecular chemistry
      Permalink
      http://hdl.handle.net/11693/38101
      Published Version (Please cite this version)
      http://dx.doi.org/10.1002/ijch.201100034
      Collections
      • Department of Chemistry 640
      • Institute of Materials Science and Nanotechnology (UNAM) 1930
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