Atropisomeric dyes: axial chirality in orthogonal bodipy oligomers

Date

2014

Authors

Kolemen, S.
Cakmak, Y.
Kostereli, Z.
Akkaya, E. U.

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Abstract

A dissymmetrically substituted orthogonal BODIPY dimer and an orthogonal BODIPY trimer exist as two stable conformers, which are in fact atropisomeric enantiomers. The racemic mixture can be separated by HPLC using a chiral stationary phase. These enantiomeric derivatives hold great potential as chiral agents in asymmetric synthesis, fluorogenic/chromogenic sensing, and biological applications.

Source Title

Organic Letters

Publisher

American Chemical Society

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Citation

Published Version (Please cite this version)

Language

English