Chemiluminescence sensing of fluoride ions using a self-immolative amplifier
Date
2014
Authors
Turan, I. S.
Akkaya, E. U.
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Abstract
An enhanced chemiluminescence signal is obtained when electronically triggered dioxetane cleavage is initiated by fluoride-mediated deprotection of the silyl-protecting group, followed by self-immolation via 1,4-quinone−methide rearrangement. The reaction takes place even when the probe is trapped within a PMMA layer on top of a glass plate. In that arrangement, fluoride in aqueous solutions can be detected selectively at low micromolar concentrations.
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Organic Letters
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American Chemical Society
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English