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      Electron spectroscopic investigation of Sn coatings on glasses

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      Author(s)
      Süzer, Ş.
      Voscoboinikov, T.
      Hallam, K. R.
      Allen, G. C.
      Date
      1996
      Source Title
      Fresenius' Journal of Analytical Chemistry
      Print ISSN
      0937-0633
      Publisher
      Springer
      Volume
      355
      Issue
      5-6
      Pages
      654 - 656
      Language
      English
      Type
      Article
      Item Usage Stats
      122
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      Abstract
      Float glasses of different thicknesses and a conducting tin oxide glass have been investigated using Photo and Auger Electron Spectroscopy induced by AlKα X-rays. On the basis of measured chemical XPS shifts in the binding energies the chemical state of Sn (+2 or +4) incorporated on the float glasses could not be assigned. The use of the Auger parameter allows to separate relaxation and chemical contributions. The derived true chemical shifts of Sn on float-glasses are larger than those of SnO and/or SnO2 due to the larger ionic environment of the glass matrix. Ar+ or HF etching reveals that the concentration of Sn decreases exponentially as a function of depth from the surface. © Springer-Verlag 1996.
      Keywords
      Auger electron spectroscopy
      Coatings
      Metals
      Tin
      Chemical shift
      Coordination number
      Float glass
      Photoelectron emission
      Thin films
      Permalink
      http://hdl.handle.net/11693/25733
      Published Version (Please cite this version)
      http://doi.org/10.1007/s0021663550654
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      • Department of Chemistry 640
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