Molecular switch based on a cucurbituril containing bistable rotaxane
Tiftik, H. B.
1369 - 1371
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A bistable CB6-based rotaxane with two recognition sites has been prepared very efficiently in a high yield synthesis through CB6 catalyzed 1,3-dipolar cycloaddition; this rotaxane behaves as a reversible molecular switch and exhibits conformational changes caused by the movement of rings under base, acid and heat stimuli from one location to the other. © The Royal Society of Chemistry.