Theoretical and spectroscopic investigations on the structure and bonding in B-C-N thin films
Genisel, M. F.
Thin Solid Films
1459 - 1464
Item Usage Stats
MetadataShow full item record
In this study, we have synthesized boron, carbon, and nitrogen containing films using RF sputter deposition. We investigated the effects of deposition parameters on the chemical environment of boron, carbon, and nitrogen atoms inside the films. Techniques used for this purpose were grazing incidence reflectance-Fourier-transform infrared spectroscopy (GIR-FTIR), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM) and electron energy loss spectroscopy (EELS). GIR-FTIR experiments on the B-C-N films deposited indicated presence of multiple features in the 600 to 1700 cm- 1 range for the infrared (IR) spectra. Analysis of the IR spectra, XPS and the corresponding EELS data from the films has been done in a collective manner. The results from this study suggested even under nitrogen rich synthesis conditions carbon atoms in the B-C-N films prefer to be surrounded by other carbon atoms rather than boron and/or nitrogen. Furthermore, we have observed a similar behavior in the chemistry of B-C-N films deposited with increasing substrate bias conditions. In order to better understand these results, we have compared and evaluated the relative stability of various nearest-neighbor and structural configurations of carbon atoms in a single BN sheet using DFT calculations. These calculations also indicated that structures and configurations that increase the relative amount of C-C bonding with respect to B-C and/or C-N were energetically favorable than otherwise. As a conclusion, carbon tends to phase-segregate in to carbon clusters rather than displaying a homogeneous distribution for the films deposited in this study under the deposition conditions studied.
Auger electron spectroscopy
Electron energy loss spectroscopy
Fourier transform infrared spectroscopy
Transmission electron microscopy
X ray photoelectron spectroscopy
Published Version (Please cite this version)http://dx.doi.org/10.1016/j.tsf.2009.09.106
Showing items related by title, author, creator and subject.
The formation and characterization of cyclodextrin functionalized polystyrene nanofibers produced by electrospinning Uyar T.; Havelund, R.; Hacaloglu J.; Zhou X.; Besenbacher F.; Kingshott P. (2009)Polystyrene (PS) nanofibers containing the inclusion complex forming beta-cyclodextrin (β-CD) were successfully produced by electrospinning aimed at developing functional fibrous nanowebs. By optimization of the electrospinning ...
Ultrasensitive electrospun fluorescent nanofibrous membrane for rapid visual colorimetric detection of H2O2 Senthamizhan A.; Balusamy, B.; Aytac Z.; Uyar T. (Springer Verlag, 2016-02)We report herein a flexible fluorescent nanofibrous membrane (FNFM) prepared by decorating the gold nanocluster (AuNC) on electrospun polysulfone nanofibrous membrane for rapid visual colorimetric detection of H2O2. The ...
Beigang, R.; Biedron, S.G.; Dyjak, S.; Ellrich F.; Haakestad, M.W.; Hübsch, D.; Kartaloglu, T.; Ozbay, E.; Ospald F.; Palka, N.; Puc, U.; Czerwiñska, E.; Sahin, A.B.; Sešek, A.; Trontelj J.; Švigelj, A.; Altan H.; Van Rheenen, A.D.; Walczakowski, M. (SPIE, 2014)We present results on the comparison of different THz technologies for the detection and identification of a variety of explosives from our laboratory tests that were carried out in the framework of NATO SET-193 THz ...