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      Mechanochemical activation and patterning of an adhesive surface toward nanoparticle deposition

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      Author
      Baytekin, H. T.
      Baytekin, B.
      Huda, S.
      Yavuz, Z.
      Grzybowski, B. A.
      Date
      2015
      Source Title
      Journal of the American Chemical Society
      Print ISSN
      0002-7863
      Electronic ISSN
      1520-5126
      Publisher
      American Chemical Society
      Volume
      137
      Issue
      5
      Pages
      1726 - 1729
      Language
      English
      Type
      Article
      Item Usage Stats
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      171
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      Abstract
      Mechanical pulling of adhesive tape creates radicals on the tapes surface. These radicals are capable of reducing metal salts to the corresponding metal nanoparticles. In this way, the mechanically activated tape can be decorated with various types of nanoparticles, including Au, Ag, Pd, or Cu. While retaining their mechanical properties and remaining "sticky, " the tapes can exhibit new properties derived from the presence of metal nanoparticles (e.g., bacteriostaticity, increased electrical conductivity). They can also be patterned with nanoparticles only at selective locations of mechanical activation.
      Keywords
      Chemical activation
      Gold
      Mechanical properties
      Nanoparticles
      Palladium
      Silver
      Adhesive surfaces
      Adhesive tapes
      Electrical conductivity
      Mechanical activation
      Mechano-chemical activation
      Metal salt
      Nanoparticle deposition
      Metal nanoparticles
      Permalink
      http://hdl.handle.net/11693/22481
      Published Version (Please cite this version)
      http://dx.doi.org/10.1021/ja507983x
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      • Department of Chemistry 594
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