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      Polystyrene / clay nanocomposites by atom transfer radical nitroxide coupling chemistry

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      Author
      Aydin, M.
      Tasdelen, M. A.
      Uyar, Tamer
      Jockusch, S.
      Turro, N. J.
      Yagci, Y.
      Date
      2013
      Source Title
      Journal of Polymer Science, Part A: Polymer Chemistry
      Print ISSN
      0887-624X
      Publisher
      Wiley
      Volume
      51
      Issue
      5
      Pages
      1024 - 1028
      Language
      English
      Type
      Article
      Item Usage Stats
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      Abstract
      An efficient protocol, atom transfer radical nitroxide coupling chemistry, for the preparation of polymer/clay nanocomposites via grafting-onto strategy with well-defined polymer, which were synthesized via atom transfer radical polymerization, has been described. The radical coupling, taking place between the clay layers, not only leads to attached polymer chains but also to successful nanocomposite formation with highly exfoliated morphology. Copyright © 2012 Wiley Periodicals, Inc.
      Keywords
      Atom transfer radical nitroxide coupling
      Atom transfer radical polymerization
      Nanocomposites
      Organoclay
      Thermal properties
      Permalink
      http://hdl.handle.net/11693/21051
      Published Version (Please cite this version)
      http://dx.doi.org/10.1002/pola.26493
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      • Institute of Materials Science and Nanotechnology (UNAM) 1831
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