Electrochromic properties of nanostructured tungsten trioxide (hydrate) films and their applications in a complementary electrochromic device
Demir, H. V.
Yang, M. F.
Sun, X. W.
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Jiao, Z., Wang, J., Ke, L., Liu, X., Demir, H. V., Yang, M. F., & Sun, X. W. (2012). Electrochromic properties of nanostructured tungsten trioxide (hydrate) films and their applications in a complementary electrochromic device. Electrochimica Acta, 63, 153-160.
Please cite this item using this persistent URLhttp://hdl.handle.net/11693/12347
Orthorhombic hydrated tungsten trioxide (3WO(3)center dot H2O) films consisted of nanosticks and nanoparticles were prepared on fluorine doped tin oxide (FTO)-coated substrate by a facile and template-free hydrothermal method using ammonium acetate (CH3COONH4) as the capping agent. Irregular nanobrick films were obtained without capping agent. Due to the highly rough surface, the nanostick/nanoparticle film depicts faster ion intercalation/deintercalation kinetics and a greater coloration efficiency (45.5 cm(2)/C) than the nanobrick film. A complementary electrochromic device based on the nanostick/nanoparticle 3WO(3)-H2O film and Prussian blue (PB) was assembled. As a result, the complementary device shows a higher optical modulation (54% at 754 nm), a larger coloration efficiency (151.9 cm(2)/C) and faster switching responses with a bleaching time of 5.7 s and a coloring time of 1.3 s than a single 3WO(3).H2O layer device, making it attractive for a practical application. (C) 2011 Elsevier Ltd. All rights reserved.