Observation of efficient transfer from Mott-Wannier to Frenkel excitons in a hybrid semiconductor quantum dot-polymer composite at room temperature
Applied Physics Letters
American Institute of Physics
263106-1 - 263106-3
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Efficient conversion from Mott-Wannier to Frenkel excitons is observed at room temperature. The time-resolved photoluminescence shows that the energy transfer rate and efficiency reach 0.262 ns-1 and 80.9%, respectively. The energy transfer is enabled by strong dipole-dipole coupling in a hybrid inorganic/organic system of CdSe/ZnS core/shell heteronanocrystal and poly[2-methoxy-5-(3,7-dimethyl-octyloxy)-1,4-phenylenevinylene] homopolymer composite, and the measured energy transfer efficiencies are consistent with the analytical model.