| dc.contributor.author | Ahmadli, D. | |
| dc.date.accessioned | 2023-02-16T10:28:58Z | |
| dc.date.available | 2023-02-16T10:28:58Z | |
| dc.date.issued | 2022-05-19 | |
| dc.identifier.issn | 0040-4039 | |
| dc.identifier.uri | http://hdl.handle.net/11693/111427 | |
| dc.description.abstract | We report the first total synthesis of the biologically active fungal natural product daldiquinone (5), which was accomplished with a longest linear sequence of 8 steps in 41% overall yield. The construction of the unsymmetrical binaphthalene core was realized by a Suzuki-Miyaura cross-coupling in 88% yield on gram scale. Oxidation of naphthol 17 with IBX afforded the key naphthoquinone intermediate 18 in high yield (92%). | en_US |
| dc.language.iso | English | en_US |
| dc.source.title | Tetrahedron Letters | en_US |
| dc.relation.isversionof | https://doi.org/10.1016/j.tetlet.2022.153877 | en_US |
| dc.subject | Daldiquinone | en_US |
| dc.subject | Naphthoquinones | en_US |
| dc.subject | Natural products | en_US |
| dc.subject | Suzuki-Miyaura coupling | en_US |
| dc.subject | Total synthesis | en_US |
| dc.title | Synthesis of the bioactive fungal natural product daldiquinone | en_US |
| dc.type | Article | en_US |
| dc.department | Institute of Materials Science and Nanotechnology (UNAM) | en_US |
| dc.citation.spage | 153877- 1 | en_US |
| dc.citation.epage | 153877- 3 | en_US |
| dc.citation.volumeNumber | 100 | en_US |
| dc.identifier.doi | 10.1016/j.tetlet.2022.153877 | en_US |
| dc.publisher | Elsevier Ltd | en_US |
| dc.contributor.bilkentauthor | Türkmen, Yunus Emre | |
| dc.embargo.release | 2024-05-19 | |
| dc.identifier.eissn | 1873-3581 | |
| buir.contributor.orcid | Türkmen, Yunus Emre|0000-0002-9797-2820 | en_US |
