Browsing by Subject "Titanium"
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Item Open Access Changes in the resistance to corrosion of thermally passivated titanium aluminide during exposure to sodium chloride solution(Kluwer Academic Publishers, 2015) Saebnoori, E.; Shahrabi, T.; Jafarian H.; Ghaffari, M.In this study the surface of Ti-47Al-2Cr (at. %) was modified by heating and exposure to nitrogen gas flow to form a predominantly oxide layer on the surface. Samples were then immersed in Ringer's solution and 3.5 wt. % sodium chloride solution and electrochemical impedance spectroscopy tests were performed at regular intervals. The results showed that the layer is highly resistant to corrosion. The equivalent circuit proposed for the impedance curves includes a Warburg element, because diffusion is controlling charge transfer through the passive surface layer. The resistance of the layer was not significantly reduced even after 300 h exposure to solutions and scanning electron micrographs showed the surface was not damaged. © 2013 Springer Science+Business Media Dordrecht.Item Open Access Çok-akışlı eşler arası isteğe bağlı video sistemlerinin Markov zinciri tabanlı güvenilirlik modellemesi(IEEE, 2008-04) Yazıcı, Mehmet Akif; Öztoprak, K.; Akar, Nail; Akar, G. B.Çok-akışlı eşler-arası video, gelecek nesil isteğe bağlı video sistemleri için kullanılmaya aday teknolojilerdendir. Çok-akışlı video sistemlerinin sorunlarından birisi, eş dalgalanması adı verilen, eşlerin ağla olan bağlantılarının kopup düzelmesi durumudur. Eş dalgalanmasının bütün eşler-arası sistemlerde olumsuz etkileri olduğu bilinmektedir. Bu etkinin hafifletilmesi için çeşitli hata kontrollü alt-akış kodlama teknikleri önerilmiştir. Bu makalede, eş dalgalanması ve hata kontrolünün rolünü incelemek amacıyla sürekli zamanlı Markov zinciri tabanlı bir rassal model önerilmektedir. Bu model kullanılarak, hata kontrolünün rolü, gelecek nesil çok-akışlı eşler-arası isteğe bağlı video sistemlerinin tasarımında kullanılmak üzere nicel olarak ortaya konmaktadır.Item Open Access Design and fabrication of micro end mills for the machining of difficult-to-cut materials(Bilkent University, 2016-08) Oliaei, Samad Nadimi BavilMicromilling is a cost-e ective method of fabricating miniaturized components with complex, three-dimensional features made from di cult-to-cut materials. Microcutting tools are exposed to harsh conditions during machining of such materials, which leads to short tool life and thus a ects the economics of the process. The aim of this thesis is to develop a systematic approach to the design and fabrication of high-precision micro-cutting tools. Machining characteristics of three di erent di cult-to-cut materials–stainless steel, titanium alloy, and silicon–have been investigated using experimental techniques. The results reveal the importance of interaction between tool micro geometry and work material mechanical properties. This observation leads to the development of tailored micro-end mills which are designed and fabricated based on the requirements of the specific machining task. This study also examines in detail built-up edge, an important but usually overlooked issue in micromachining of ductile materials, which a ects the process forces, tool wear, and tool deflections. The protective e ect of built-up edge has been exploited by creating micro-dimples on the tool surface using electrical discharge machining. Its positive influence on tool performance has been demonstrated. As for the micromachining of silicon, the flow of cut material around the cutting edge is paramount in tool design. A novel tool design for machining of silicon has been proposed and its e ectiveness has been validated through experiments. It has been shown that the selection of proper process parameters together with tailored tool design may increase the productivity of micromachining and improve surface quality and dimensional accuracy of micro-scale parts.Item Open Access Effects of charging and electric field on graphene functionalized with titanium(Institute of Physics Publishing, 2013) Gürel, H. H.; Çıracı, SalimTitanium atoms are adsorbed to graphene with a significant binding energy and render diverse functionalities to it. Carrying out first-principles calculations, we investigated the effects of charging and static electric field on the physical and chemical properties of graphene covered by Ti adatoms. When uniformly Ti covered graphene is charged positively, its antiferromagnetic ground state changes to ferromagnetic metal and attains a permanent magnetic moment. Static electric field applied perpendicularly causes charge transfer between Ti and graphene, and can induce metal-insulator transition. While each Ti adatom adsorbed to graphene atom can hold four hydrogen molecules with a weak binding, these molecules can be released by charging or applying electric field perpendicularly. Hence, it is demonstrated that charging and applied static electric field induce quasi-continuous and side specific modifications in the charge distribution and potential energy of adatoms absorbed to single-layer nanostructures, resulting in fundamentally crucial effects on their physical and chemical properties. © 2013 IOP Publishing Ltd.Item Open Access Effects of milling and annealing on formation and structural characterization of nanocrystalline intermetallic compounds from Ni-Ti elemental powders(2012) Ghadimi, M.; Shokuhfar, A.; Rostami H.R.; Ghaffari, M.Nickel and Titanium elemental powders with a nominal composition Ni-50 at.%Ti were mechanical alloyed in a planetary high-energy ball mill in different milling conditions (5, 10, 20, 40 and 60 h). The investigation revealed that increasing milling time leads to a reduction in crystallite size, and after 60 h of milling, the Ti dissolved in Ni lattice and NiTi (B2) phase was obtained. With milling time, morphology of pre-alloyed powders changed from lamella to globular. Annealing of as-milled powders at 1173 K for 900 s led to formation of nanocrystalline NiTi (B19′), grain growth and release of internal strain. The results indicated that this technique is a powerful and high productive process for preparing NiTi intermetallic compound with nanocrystalline structure and appropriate morphology. © 2012 Elsevier B.V. All rights reserved.Item Open Access Evaluate of braze joint strength and microstructure characterize of titanium-CP with Ag-based filler alloy(2012) Ganjeh, E.; Sarkhosh H.; Khorsand H.; Sabet H.; Dehkordi, E.H.; Ghaffari, M.This research investigates the influences of brazing parameters (temperature and time) on microstructures and the mechanical properties of commercially pure (CP) titanium sheet when it is brazed with CBS34 (Ag-20Cu-22Zn-24Cd) braze filler foil. Brazing was performed in a conventional atmosphere control furnace. The brazing temperatures and holding times employed in this study were 800-870°C and 10-20min, respectively. The qualities of the brazed joints were evaluated by ultrasonic test and the microstructure and phase constitution of the bonded joints were analyzed by means of metallography, scanning electron microscope (SEM) and X-ray diffraction (XRD). The mechanical properties of brazed joints were evaluated by microhardness and shear tests. The diffusion between Ti, Ag, Cu, Zn and Cd from substrate and braze alloy, developed a strong reaction between each other. A number of intermetallic phases, such as TiCu and Ti2Cu in the Ag-Zn solid solution matrix have been identified especially at 870°C - 20min. Both the brazing temperature and the holding time are critical factors for controlling the microstructure and hence the mechanical properties of the brazed joints. The optimum brazing parameters was achieved at 870°C - 20min. Based on the shear test result, all cracks propagate along the brittle intermetallic compounds like Ti2Cu in the reaction layer which typically are composed of quasi-cleavage (Ag-Zn matrix) and brittle appearance. © 2012 Elsevier Ltd.Item Open Access Femtosecond laser-induced TiO2 nano structures on titanium(Optical Society of America, 2010) Öktem, Bülent; Kalaycıoğlu, Hamit; İlday, F. ÖmerWe report formation of polarization-dependent nanostructures (nanolines, nanocircles) by high repetition-rate femtosecond laser pulses on titanium surface through a novel mechanism, converting Ti to TiO2. Arbitrarily large-area patterns are created by self-stitching of these patterns. © 2010 Optical Society of America.Item Open Access High conducting nanowires obtained from uniform titanium covered carbon nanotubes(2005) Daǧ, Sefa; Durgun, Engin; Çıracı, SalimWe have shown that Ti atoms can form continuous coating of carbon nanotubes at different amount of coverage. The circular cross section changes to a square-like form, and the semiconducting tube becomes ferromagnetic metal with high quantum ballistic conductance. Metallicity is induced not only by the metal-metal coupling, but also by the band gap closing of SWNT at the corners of the square. The magnetic properties of Ti coated tubes depend strongly on the geometry, amount of Ti coverage and also on the elastic deformation of the tube. While the magnetic moment can be pronounced significantly by the positive axial strain, it can decrease dramatically upon the adsorption of additional Ti atoms to those already covering the nanotube. Besides, electronic structure and spin-polarization near the Fermi level can also be modified by radial strain. Our results have been obtained by the first-principles, spin-relaxed pseudopotential plane wave calculations within the density functional theory. © TÜBİTAK.Item Open Access High-conducting magnetic nanowires obtained from uniform titanium-covered carbon nanotubes(American Physical Society, 2004) Daǧ, Sefa; Durgun, Engin; Çıracı, SalimWe have shown that a semiconducting single-wall carbon nanotube (SWNT) can be covered uniformly by titanium atoms and form a complex but regular atomic structure. The circular cross section changes to a squarelike form, and the system becomes metallic with high state density at the Fermi level and with high quantum ballistic conductance. Metallicity is induced not only by the metal-metal coupling, but also by the band-gap closing of SWNT's at the corners of the square. Even more interesting is that uniform titanium-covered tubes have magnetic ground state with significant net magnetic moment. Our results have been obtained by the first-principles pseudopotential plane-wave calculations within the density-functional theory.Item Open Access Hydrogenation of naphthalene and methylnaphthalene: modeling and spectroscopy(Elsevier BV, 2002) Sayan, Ş.; Paul, J.In situ infrared spectra of 1-methylnaphthalene (1-MeNapht)hydrogenation, over sulfided NiMo/Al2O3-TiO2 catalysts, were compared with theoretically derived properties of methylnaphthalene and its bicyclic products: MeDilin, MeTetralin, MeOctalin and MeDecalin, and with conversion data from literature. Comparisons were also made between the un-substituted and methyl-substituted two-rings, and between the 1- and 5-methyl isomers of 1,4-dihydronaphthalene (dilin) and 1,2,3,4-tetrahydronaphthalene (tetralin). IR spectra of MeNapht adsorption, on the sulfided catalyst, were matched with data for adsorption on the catalyst without sulfidation and the empty support. Surface bound MeNapht is observed below 250°C on all catalysts. MeNapht adsorption suppresses OH groups nondiscriminatory on the empty support and the metal loaded catalyst. We relate the results to previous data on the interaction between the supported metal sulfides and titanium modified aluminas. Calculated total energies, and experimentally derived heats of formation, pointed at decahydronaphthalene (decalin) as the dominant product of naphthalene hydrogenation, with tetralin as an abundant intermediate, and dilin and 1,2,3,4,5,6,7,8-octahydronaphthalene (octalin) as short lived transient stages. The spectroscopic modeling showed that the orbital fingerprints of the five bicyclic compounds were not distinctly different, nor more than marginally modified by methyl substitution or isomerization. The only significant difference came at the highest occupied orbital, where a high naphthalene density of states (DoS) overlapped with the valence bands of metal or metal sulfide catalysts. The vibrational bands for naphthalene, dilin, tetralin and octalin were well separated. Octalin and decalin, alone, have similar vibrational spectra. Upheaval of ring degeneracy for methyl-substituted two-ring structures broadened all infrared bands in a characteristic way.Item Open Access Increasing Ti-6Al-4V brazed joint strength equal to the base metal by Ti and Zr amorphous filler alloys(2012) Ganjeh, E.; Sarkhosh H.; Bajgholi, M.E.; Khorsand H.; Ghaffari, M.Microstructural features developed along with mechanical properties in furnace brazing of Ti-6Al-4V alloy using STEMET 1228 (Ti-26.8Zr-13Ni-13.9Cu, wt.%) and STEMET 1406 (Zr-9.7Ti-12.4Ni-11.2Cu, wt.%) amorphous filler alloys. Brazing temperatures employed were 900-950 °C for the titanium-based filler and 900-990 °C for the zirconium-based filler alloys, respectively. The brazing time durations were 600, 1200 and 1800 s. The brazed joints were evaluated by ultrasonic test, and their microstructures and phase constitutions analyzed by metallography, scanning electron microscopy and X-ray diffraction analysis. Since microstructural evolution across the furnace brazed joints primarily depends on their alloying elements such as Cu, Ni and Zr along the joint. Accordingly, existence of Zr 2Cu, Ti 2Cu and (Ti,Zr) 2Ni intermetallic compounds was identified in the brazed joints. The chemical composition of segregation region in the center of brazed joints was identical to virgin filler alloy content which greatly deteriorated the shear strength of the joints. Adequate brazing time (1800 s) and/or temperature (950 °C for Ti-based and 990 °C for Zr-based) resulted in an acicular Widmanstätten microstructure throughout the entire joint section due to eutectoid reaction. This microstructure increased the shear strength of the brazed joints up to the Ti-6Al-4V tensile strength level. Consequently, Ti-6Al-4V can be furnace brazed by Ti and Zr base foils produced excellent joint strengths. © 2012 Elsevier Inc. All rights reserved.Item Open Access Investigating the influence of built-up edge on forces and surface roughness in micro scale orthogonal machining of titanium alloy Ti6Al4V(Elsevier, 2016) Oliaei, S. N. B.; Karpat, Y.The edge geometry of cutting tools directly influences the chip formation mechanism in micro-mechanical machining, where the edge radius and uncut chip thickness are in the same order of magnitude. An uncut chip thickness that is smaller than the cutting edge radius results in a large negative rake angle during machining, and built-up edge formation then affects the mechanics of the process. In this study, micro-scale orthogonal cutting tests on titanium alloy Ti6Al4V were conducted to investigate the influence of built-up edge formation on the machining forces and surface roughness. Cutting edges in these tests are engineered using wire EDM technique to have an edge radius of around 2 μm and clearance angles of 7° and 14°. It is observed that machining process inputs (uncut chip thickness, cutting speed, and clearance angle) affect the size of the built-up edge, which in turn affect the process outputs. It is observed that built-up edge formation protects the cutting edge from flank and crater wear under micro machining conditions and the influence of built-up edge on the surface roughness varies depending on the cutting speed and uncut chip thickness. Our findings also indicate a close relationship between the minimum uncut chip thickness and the mean roughness depth (Rz) of the machined surface. The minimum uncut chip thickness is found to be around 10% of the edge radius in the presence of built-up edge.Item Open Access Investigation on braze joint strength and microstructure of Ti-CP with Ag and Ti base filler alloys(American Welding Society, 2012) Ganjeh, E.; Khorsand H.; Sarkhosh H.; Ghaffari, M.; Sabet H.; Dehkordi, E.H.This research investigates influences of brazing parameters (brazing alloy, temperature and time) on microstructures and mechanical properties of a commercially pure (CP) titanium sheet which is brazed with CBS 34 (Ag-based) and STEMET 1228 (Ti-based) braze-filler foils. Brazing was performed in a conventional inert furnace at temperature ranges of 800-870°C and 10-30 minutes for holding times. Qualities of the brazed joints were evaluated by ultrasonic testing, and then, microstructure and phase constitution of the bonded joints were analyzed by means of metallography, scanning electron microscope (SEM), and X-ray diffraction (XRD). Mechanical properties of brazed joints were evaluated by shear testing. Diffusion of titanium from substrate to filler alloy developed a strong reaction between them. A number of phases such as TiCu, Ti 2Cu, TiAg, Ag-Zn solid solution matrix (for Ag-based brazed samples) and Ti 2Cu, (Ti,Zr) 2Ni, Zr 2Cu (for Ti-based brazed samples) have been identified. The optimum brazing parameters were achieved at a temperature of 870 °C-20 min for CBS 34 and 870 °C-30 min for STEMET 1228. The specimen using STEMET 1228 braze alloy demonstrates best bonding strength (equal to Ti-CP tensile strength). Copyright 2012 ASM International® All rights reserved.Item Open Access A modified material model for the finite element simulation of machining titanium alloy Ti-6Al-4V(Taylor & Francis, 2010) Karpat, Y.Because of their desirable properties, such as high strength to weight ratio and corrosion resistance, titanium alloys are commonly employed in the aerospace and medical device industries. Titanium alloys are known to be difficult to machine, so the selection of cutting conditions with minimal experimental effort is important for manufacturers. Finite element modeling, which is an indispensable tool to understand the mechanics of machining, can also be utilized as an alternative method of process design as long as the finite element simulation input parameters are well defined. Developing a modified material model for titanium alloy Ti-6Al-4V by considering the relationships between strain, strain rate and temperature is the subject of this study. The flow softening behavior of the material at high strains is also examined. The influences of the material model parameters on the finite element simulation outputs are investigated. The finite element simulation results are found to be in agreement with the data available in the literature.Item Open Access Nanoscale selective area atomic layer deposition of TiO2 using e-beam patterned polymers(Royal Society of Chemistry, 2016) Haider A.; Yilmaz, M.; Deminskyi, P.; Eren, H.; Bıyıklı, NecmiHere, we report nano-patterning of TiO2via area selective atomic layer deposition (AS-ALD) using an e-beam patterned growth inhibition polymer. Poly(methylmethacrylate) (PMMA), polyvinylpyrrolidone (PVP), and octafluorocyclobutane (C4F8) were the polymeric materials studied where PMMA and PVP were deposited using spin coating and C4F8 was grown using inductively coupled plasma (ICP) polymerization. TiO2 was grown at 150 °C using tetrakis(dimethylamido) titanium (TDMAT) and H2O as titanium and oxygen precursors, respectively. Contact angle, scanning electron microscopy (SEM), spectroscopic ellipsometry, and X-ray photoelectron spectroscopy (XPS) measurements were performed to investigate the blocking/inhibition effectiveness of polymer layers for AS-ALD of TiO2. TiO2 was grown with different numbers of growth cycles (maximum = 1200 cycles) on PMMA, PVP, and C4F8 coated substrates, where PMMA revealed complete growth inhibition up to the maximum number of growth cycles. On the other hand, PVP was able to block TiO2 growth up to 300 growth cycles only, whereas C4F8 showed no TiO2-growth blocking capability. Finally, mm-, μm-, and nm-scale patterned selective deposition of TiO2 was demonstrated exploiting a PMMA masking layer that has been patterned using e-beam lithography. SEM, energy-dispersive X-ray spectroscopy (EDX) line scan, EDX elemental mapping, and XPS line scan measurements cumulatively confirmed the self-aligned deposition of TiO2 features. The results presented for the first time demonstrate the feasibility of achieving self-aligned TiO2 deposition via TDMAT/H2O precursor combination and e-beam patterned PMMA blocking layers with a complete inhibition for >50 nm-thick films.Item Open Access Photocatalytic conversion of nitric oxide on titanium dioxide: cryotrapping of reaction products for online monitoring by mass spectrometry(American Chemical Society, 2016) Lu, W.; Olaitan, A. D.; Brantley, M. R.; Zekavat, B.; Erdogan, D. A.; Ozensoy, E.; Solouki, T.Details of coupling a catalytic reaction chamber to a liquid nitrogen-cooled cryofocuser/triple quadrupole mass spectrometer for online monitoring of nitric oxide (NO) photocatalytic reaction products are presented. Cryogenic trapping of catalytic reaction products, via cryofocusing prior to mass spectrometry analysis, allows unambiguous characterization of nitrous oxide (N2O) and nitrogen oxide species (i.e., NO and nitrogen dioxide (NO2)) at low concentrations. Results are presented, indicating that the major photocatalytic reaction product of NO in the presence of titanium dioxide (TiO2) P25 and pure anatase catalysts when exposed to ultraviolet (UV) light (at a wavelength of 365 nm) is N2O. However, in the presence of rutile-rich TiO2 catalyst and UV light, the conversion of NO to N2O was less than 5% of that observed with the P25 or pure anatase TiO2 catalysts.Item Open Access Self-assembled template-directed synthesis of one-dimensional silica and titania nanostructures(2011) Acar H.; Garifullin, R.; Güler, Mustafa O.Mineralized biological materials such as shells, skeleton, and teeth experience biomineralization. Biomimetic materials exploit the biomineralization process to form functional organic-inorganic hybrid nanostructures. In this work, we mimicked the biomineralization process by the de novo design of an amyloid-like peptide that self-assembles into nanofibers. Chemically active groups enhancing the affinity for metal ions were used to accumulate silicon and titanium precursors on the organic template. The self-assembly process and template effect were characterized by CD, FT-IR, UV-vis, fluorescence, rheology, TGA, SEM, and TEM. The self-assembled organic nanostructures were exploited as a template to form high-aspect-ratio 1-D silica and titania nanostructures by the addition of appropriate precursors. Herein, a new bottom-up approach was demonstrated to form silica and titania nanostructures that can yield wide opportunities to produce high-aspect-ratio inorganic nanostructures with high surface areas. The materials developed in this work have vast potential in the fields of catalysis and electronic materials. © 2011 American Chemical Society.Item Open Access The substrate temperature dependent electrical properties of titanium dioxide thin films(2010) Yildiz, A.; Lisesivdin, S.B.; Kasap, M.; Mardare, D.Titanium dioxide thin films were obtained by a dc sputtering technique onto heated glass substrates. The relationship between the substrate temperature and the electrical properties of the films was investigated. Electrical resistivity measurements showed that three types of conduction channels contribute to conduction mechanism in the temperature range of 13-320 K. The temperature dependence of electrical resistivity between 150 and 320 K indicated that electrical conductioninthe films was controlled by potential barriers caused by depletion of carriers at grain boundaries. The conduction mechanism of the films was shifted from grain boundary scattering dominated band conduction to the nearest neighbor hopping conduction at temperatures between 55 and 150 K. Below 55 K, the temperature dependence of electrical resistivity shows variable range hopping conduction. The correlation between the substrate temperature and resistivity behaviorisdiscussed by analyzing the physical plausibility of the hopping parameters and material properties derived by applying different conduction models. With these analyses, various electrical parameters of the present samples such as barrier height, donor concentration, density of states at the Fermi level, acceptor concentration and compensation ratio were determined. Their values as a function of substrate temperature were compared. © Springer Science+Business Media, LLC 2009.Item Open Access Systematic study of adsorption of single atoms on a carbon nanotube(American Physical Society, 2003) Durgun, Engin; Dag, S.; Bagci, V. M. K.; Gülseren, O.; Yildirim, T.; Çıracı, SalimWe studied the adsorption of single atoms on a semiconducting and metallic single-wall carbon nanotube from first principles for a large number of foreign atoms. The stable adsorption sites, binding energy, and the resulting electronic properties are analyzed. The character of the bonding and associated physical properties exhibit dramatic variations depending on the type of the adsorbed atom. While the atoms of good conducting metals, such as Cu and Au, form very weak bonding, atoms such as Ti, Sc, Nb, and Ta are adsorbed with relatively high binding energy. Most of the adsorbed transition-metal atoms excluding Ni, Pd, and Pt have a magnetic ground state with a significant magnetic moment. Our results suggest that carbon nanotubes can be functionalized in different ways by their coverage with different atoms, showing interesting applications such as one-dimensional nanomagnets or nanoconductors and conducting connects, etc.Item Open Access Texturing of titanium (Ti6Al4V) medical implant surfaces with MHz-repetition-rate femtosecond and picosecond Yb-doped fiber lasers(Optical Society of American (OSA), 2011) Erdoǧan, M.; Öktem, B.; Kalaycioǧlu H.; Yavaş, S.; Mukhopadhyay P.K.; Eken, K.; Özgören, K.; Aykaç, Y.; Tazebay, U.H.; Ilday F.O.We propose and demonstrate the use of short pulsed fiber lasers in surface texturing using MHz-repetition-rate, microjoule- and sub-microjoule-energy pulses. Texturing of titanium-based (Ti6Al4V) dental implant surfaces is achieved using femtosecond, picosecond and (for comparison) nanosecond pulses with the aim of controlling attachment of human cells onto the surface. Femtosecond and picosecond pulses yield similar results in the creation of micron-scale textures with greatly reduced or no thermal heat effects, whereas nanosecond pulses result in strong thermal effects. Various surface textures are created with excellent uniformity and repeatability on a desired portion of the surface. The effects of the surface texturing on the attachment and proliferation of cells are characterized under cell culture conditions. Our data indicate that picosecond-pulsed laser modification can be utilized effectively in low-cost laser surface engineering of medical implants, where different areas on the surface can be made cell-attachment friendly or hostile through the use of different patterns. © 2011 Optical Society of America.