Browsing by Subject "Ternary systems"
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Item Open Access High-performance solar-blind AlGaN photodetectors(SPIE, 2005) Özbay, Ekmel; Tut, Turgut; Bıyıklı, N.Design, fabrication, and characterization of high-performance Al xGa1-xN-based photodetectors for solar-blind applications are reported. AlxGa1-xN heterostructures were designed for Schottky, p-i-n, and metal-semiconductor-metal (MSM) photodiodes. The solar-blind photodiode samples were fabricated using a microwave compatible fabrication process. The resulting devices exhibited extremely low dark currents. Below 3 fA leakage currents at 6 V and 12 V reverse bias were measured on p-i-n and Schottky photodiode samples respectively. The excellent current-voltage (I-V) characteristics led to a detectivity performance of 4.9×1014 cmHz1/2W-1. The MSM devices exhibited photoconductive gain, while Schottky and p-i-n samples displayed 0.15 A/W and 0.11 A/W peak responsivity values at 267 nm and 261 nm respectively. All samples displayed true solar-blind response with cut-off wavelengths smaller than 280 nm. A visible rejection of 4×104 was achieved with Schottky detector samples. High speed measurements at 267 nm resulted in fast pulse responses with >GHz bandwidths. The fastest devices were MSM photodiodes with a maximum 3-dB bandwidth of 5.4 GHz.Item Open Access Micromachined III-V cantilevers for AFM-tracking scanning Hall probe microscopy(Institute of Physics, 2003) Brook, A. J.; Bending, S. J.; Pinto, J.; Oral, A.; Ritchie, D.; Beere, H.; Springthorpe, A.; Henini, M.In this paper we report the development of a new III-V cantilever-based atomic force sensor with piezoresistive detection and an integrated Hall probe for scanning Hall probe microscopy. We give detailed descriptions of the fabrication process and characterization of the new integrated sensor, which will allow the investigation of magnetic samples with no sample preparation at both room and cryogenic temperatures. We also introduce a novel piezoresistive material based on the ternary alloy n+-Al0.4Ga0.6As which allows us to achieve a cantilever deflection sensitivity ΔR/(RΔz) = 2 × 10-6 Å-1 at room temperature.Item Open Access Role of organic and inorganic additives on the assembly of CTAB-P123 and the morphology of mesoporous silica particles(2009) Poyraz, A. S.; Dag, Ö.Mesoporous silica particles with various morphologies and structures have been synthesized by controlling the solubility, micellization, and assembly of a charged surfactant (cethyltrimethylammonium bromide, CTAB) and a pluronic (PEO20PPO70PEO20, P123) couple using an organic (benzene) or an inorganic (SO4 2-, NO3 -, or Cl-) additive. The effect of CTAB, with or without one of the Hofmeister ions or benzene in various concentrations, on the morphology, pore-size, pore-structure and the nature of the silica particles has been investigated. Increasing the lyotropic anion (SO4 2-) or benzene concentration of the synthesis media creates wormlike particles with enlarged pores and reduced wall thickness. However, the hydrotropic anion (NO3 -) influenced the solubility of the charged surfactant and increased the CTAB concentration in the CTAB-P123 micelles, and as a result, in the mesoporous silica particles. The surface area, unit cell, and pore size of the silica particles are diminished by increasing the nitrate ion centration. The effects of the Cl- ion are between the SO4 2- and NO3 -ions. It influenced the P123 at low and CTAB at high concentrations. At low CTAB/ P123 mol ratios, the Cl- ion affects mainly the P123, but at high CTAB/P123 it affects both the CTAB and P123. By carefully adjusting these ingredients (CTAB, SO4 2-, Cl-, NO3 - and benzene), not only the morphology of the particles, but also the pore-size and pore-structure of the mesoporous silica particles could be adjusted. The investigations were carried out by preparing a series of powder samples and, by varying the CTAB/P123 mol ratio (between 3.0 and 6.0) and the concentration of the organic (0.17 to 0.90 M) or inorganic (at 0.25, 0.50, or 1.00 M) additive in the synthesis media. The powder samples were analyzed using microscopy (SEM, TEM, and POM), diffraction (PXRD), and spectroscopy (FTIR, Raman, UV-vis, and EDS) techniques toward above goals. © 2009 American Chemical Society.Item Open Access Spectroscopic investigation of nitrate-metal and metal-surfactant interactions in the solid AgNO3/C12EO10 and liquid-crystalline [M(H2O)n](NO3)2/C12EO10 systems(American Chemical Society, 2003) Dag, Ö.; Samarskaya, O.; Tura, C.; Günay, A.; Çelik, Ö.Interactions of the nitrate ions in various metal nitrate salts with CnH2n-1(CH2CH2O)mOH (CnEOm)-type nonionic surfactants have been investigated both in the solid and in the liquid-crystalline (LC) systems. In the ternary system, the mixture of salt/water/CnEOm has a mesophase up to a certain concentration of salt, and the nitrate ions in this phase are usually in a free-ion form. However, upon the evaporation of the water phase, the nitrate ion interacts with the metal center and coordinates as either a bidentate or unidentate ligand. It is this interaction that makes the AgNO3 ternary system undergo a phase separation by releasing solid Ag(CnEOm)xNO3 complex crystals. In contrast, the salt/surfactant systems maintain their stable LC phases for months. Note also that the salt/surfactant systems consist of transition-metal aqua complexes in which the coordinated water molecules play a significant role in the self-assembly and organization of the nonionic surfactant molecules into an LC mesophase. Throughout this work, Fourier transform infrared spectroscopy has been extensively used to investigate the interactions of the nitrate ions with a metal center and the metal ions with the surfactant molecules. Polarized optical microscopy and X-ray diffraction techniques have been applied to investigate the nature of the crystalline and LC phases.