Browsing by Subject "Argon"
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Item Open Access 30-fs 1.6 mJ pulses at a kHz repetition rate from a single stage DPSS Yb amplifier(OSA, 2010) Andriukaitis, G.; Kartashov, D.; Pugzlys, A.; Lorenc, D.; Baltuska, A.; Giniunas, L.; Danielius, R.; İlday, Ömer Fatih200-fs 2.5-mJ pulses from a cw-diode-pumped Yb:CaF2 MOPA are spectrally broadened in Ar and recompressed to 30 fs at 980 nm using a prism pair. Multi-millijoule 12-fs pulses are feasible upon higher-order spectral phase correction.Item Open Access Effects of thickness on the metal-insulator transition in free-standing vanadium dioxide nanocrystals(American Chemical Society, 2017) Fadlelmula, M. M.; Sürmeli, E. C.; Ramezani, M.; Kasırga, T. S.Controlling solid state phase transitions via external stimuli offers rich physics along with possibilities of unparalleled applications in electronics and optics. The well-known metal-insulator transition (MIT) in vanadium dioxide (VO2) is one instance of such phase transitions emerging from strong electronic correlations. Inducing the MIT using electric field has been investigated extensively for the applications in electrical and ultrafast optical switching. However, as the Thomas-Fermi screening length is very short, for considerable alteration in the material’s properties with electric field induced MIT, crystals below 10 nm are needed. So far, the only way to achieve thin crystals of VO2 has been via epitaxial growth techniques. Yet, stress due to lattice mismatch as well as interdiffusion with the substrate complicate the studies. Here, we show that free-standing vapor-phase grown crystals of VO2 can be milled down to the desired thickness using argon ion-beam milling without compromising their electronic and structural properties. Among our results, we show that even below 4 nm thickness the MIT persists and the transition temperature is lowered in two-terminal devices as the crystal gets thinner. The findings in this Letter can be applied to similar strongly correlated materials to study quantum confinement effects.Item Open Access Framework for online superimposed event detection by sequential Monte Carlo methods(IEEE, 2008-03-04) Urfalıoğlu, Onay; Kuruoğlu, E. E.; Çetin, A. EnisIn this paper, we consider online seperation and detection of superimposed events by applying particle filtering. We concentrate on a model where a background process, represented by a 1D-signal, is superimposed by an Auto-Regressive (AR) 'event signal', but the proposed approach is applicable in a more general setting. The activation and deactivation times of the event-signal are assumed to be unknown. We solve the online detection problem of this superpositional event by extending the state space dimension by one. The additional parameter of the state represents the AR-signal, which is zero when deactivated. Numerical experiments demonstrate the effectiveness of our approach. ©2008 IEEE.Item Open Access Phase transformation during mechano-synthesis of nanocrystalline/amorphous Fe–32Mn–6Si alloys(Elsevier, 2013) Amini, R.; Shamsipoor, A.; Ghaffari, M.; Alizadeh, M.; Okyay, Ali KemalMechano-synthesis of Fe-32Mn-6Si alloy by mechanical alloying of the elemental powder mixtures was evaluated by running the ball milling process under an inert argon gas atmosphere. In order to characterize the as-milled powders, powder sampling was performed at predetermined intervals from 0.5 to 192 h. X-ray florescence analyzer, X-ray diffraction, scanning electron microscope, and high resolution transmission electron microscope were utilized to investigate the chemical composition, structural evolution, morphological changes, and microstructure of the as-milled powders, respectively. According to the results, the nanocrystalline Fe-Mn-Si alloys were completely synthesized after 48 h of milling. Moreover, the formation of a considerable amount of amorphous phase during the milling process was indicated by quantitative X-ray diffraction analysis as well as high resolution transmission electron microscopy image and its selected area diffraction pattern. It was found that the α-to-γ and subsequently the amorphous-to-crystalline (especially martensite) phase transformation occurred by milling development.Item Open Access Superimposed event detection by sequential Monte Carlo methods(IEEE, 2007) Urfalıoğlu, O.; Kuruoğlu, E. E.; Çetin, A. EnisIn this paper, we consider the detection of rare events by applying particle filtering. We model the rare event as an AR signal superposed on a background signal. The activation and deactivation times of the AR-signal are unknown. We solve the online detection problem of this superpositional rare event by extending the state space dimension by one. The additional parameter of the state represents the AR-signal, which is zero when deactivated. Numerical experiments demonstrate the effectiveness of our approach.Item Open Access Time-related wettability characteristic of acrylic resin surfaces treated by glow discharge(Elsevier, 1999-12) Özden, N.; Akaltan, F.; Süzer, Şefik; Akovali, G.STATEMENT OF PROBLEM: Adhesion and cohesion have important roles in denture retention, and attempts have been made to improve the wettability of the acrylic resin material by surface treatments. PURPOSE: This study examined the initial and subsequent wettability of an acrylic resin denture base material treated under air or argon plasma atmosphere before and after exposure to air or distilled water. MATERIAL AND METHODS: Acrylic resin specimens were treated with plasma under air or argon atmosphere and were either exposed to air or distilled water for up to 60 days. Wettability characteristics of the acrylic resin specimens were determined by contact-angle measurements after 2 hours and after 60 days. Surface composition of the specimens also was analyzed with x-ray photoelectron spectroscopic (XPS) measurements. RESULTS: Statistically significant difference was found between control and each of the plasma treatment groups (P <.05). Although the storage condition and storage period caused statistically significant difference on contact angle values (P <.05), atmosphere type did not have any effect on the results (P >.05). XPS spectra of the plasma-treated specimens differed from control specimens only in the O1s region with a narrower and more intense peak that could be assigned to -COH groups. During 60 days of exposure, the O/C atomic ratios decreased within the first 2 weeks but settled to 0.40 and 0. 32 up to 60 days compared with 0.26 for untreated control specimens. CONCLUSION: Glow discharge plasma altered the surfaces of the acrylic resin and increased thc wettability as shown both by XPS and contact-angle measurements, and plasma treatment seemed to offer a durable (at least up to 60 days) wettability.Item Open Access Use of saccharides as solid-state precursors for the synthesis of carbon nanotubes(Materials Research Society, 2008) Küçükkayan, Gökçe; Kayacan, Serim; Baykal, Beril; Bengu, ErmanSaccharides, ranging from simple table sugar (sucrose) to lactulose were successfully used as solid-state precursors for the synthesis of multi-walled carbon nanotubes (MWCNT). Dehydrated saccharide residues mixed with catalyst powders were subjected to pyrolysis at high temperatures (up to 1300°C) under flowing Argon atmosphere. Pyrolysis products were investigated using TEM, SEM, Raman spectroscopy and EDS. Images taken using the S/TEM and bright field mode of TEM showed the presence of helical multi-walled carbon nanotube (H-MWCNT) and regular MWCNT formation. More than two or three catalyst particles were observed to be present inside the hollow core of some of the nanotubes synthesized, suggesting a high level of capillary activity inside the tubes during synthesis. © 2008 Materials Research Society.