Browsing by Author "Yildiz, E."
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Item Open Access RuO2 supercapacitor enables flexible, safe, and efficient optoelectronic neural interface(Wiley-VCH Verlag GmbH & Co. KGaA, 2022-08-01) Karatum, O.; Yildiz, E.; Kaleli, H. N.; Sahin, A.; Ulgut, Burak; Nizamoglu, S.Optoelectronic biointerfaces offer a wireless and nongenetic neurostimulation pathway with high spatiotemporal resolution. Fabrication of low-cost and flexible optoelectronic biointerfaces that have high photogenerated charge injection densities and clinically usable cell stimulation mechanism is critical for rendering this technology useful for ubiquitous biomedical applications. Here, supercapacitor technology is combined with flexible organic optoelectronics by integrating RuO2 into a donor–acceptor photovoltaic device architecture that facilitates efficient and safe photostimulation of neurons. Remarkably, high interfacial capacitance of RuO2 resulting from reversible redox reactions leads to more than an order-of-magnitude increase in the safe stimulation mechanism of capacitive charge transfer. The RuO2-enhanced photoelectrical response activates voltage-gated sodium channels of hippocampal neurons and elicits repetitive, low-light intensity, and high-success rate firing of action potentials. Double-layer capacitance together with RuO2-induced reversible faradaic reactions provide a safe stimulation pathway, which is verified via intracellular oxidative stress measurements. All-solution-processed RuO2-based biointerfaces are flexible, biocompatible, and robust under harsh aging conditions, showing great promise for building safe and highly light-sensitive next-generation neural interfaces.Item Open Access Synthesis of a novel poly(arylene ether ketone) and its conducting composites with polypyrrole(Elsevier, 1997) Selampinar, F.; Akbulut, U.; Yildiz, E.; Güngör, A.; Toppare, L.The synthesis of a 1,3-bis(4-fluorobenzoyl)-5-tert-butyl benzene and hexafluoro bisphenol A based poly(arylene ether ketone) (PEK) was described. The electrically conductive composites of polypyrrole (PPy) and PEK were formed by electropolymerization of pyrrole on a PEK coated platinum electrode in a medium containing water andp-toluenesulfonic acid as the solvent and the electrolyte, respectively. The electrical conductivity of the composites was found to be between 1 and 4 S/cm. The polypyrrole/poly (ether ketone) composites were characterized by scanning electron microscopy, FT-IR and thermal analyses (TGA, DSC). © 1997 Elsevier Science S.A.