Browsing by Author "Kocabaş, C."
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Item Open Access Fourier transform plasmon resonance spectrometer using nanoslit-nanowire pair(American Institute of Physics, 2019) Uulu, Doolos Aibek; Ashirov, Timur; Polat, N.; Yakar, O.; Balcı, S.; Kocabaş, C.In this paper, we present a nanoscale Fourier transform spectrometer using a plasmonic interferometer consisting of a tilt subwavelength slit-nanowire pair on a metallic surface fabricated by the focused ion beam microfabrication technique. The incident broadband light strongly couples with the surface plasmons on the gold surface, and thus, surface plasmon polaritons (SPPs) are generated. The launched SPPs interfere with the incident light and generate high contrast interference fringes in the nanoslit. The transmitted SPPs through the metal nanoslit can decouple into free space and are collected by an objective in the far field. The spectroscopic information of the incidence light is obtained by fast Fourier transform of the fringe pattern of the SPPs. In our design, there is no need for a bulky dispersive spectrometer or dispersive optical elements. The dimension of the spectrometer is around 200 μm length. Our design is based on inherent coherence of the SPP waves propagating through the subwavelength metal nanoslit structures etched into an opaque gold film.Item Open Access Localized X-ray photoelectron impedance spectroscopy (LoXPIS) for capturing charge dynamics of an ionic liquid electrolyte within an energy storage device(Royal Society of Chemistry, 2022-01-12) Başaran, M.; Öz, E.; Ergöktaş, S.; Kocabaş, C.; Ülgüt, B.; Kocabas, A.; Süzer, ŞefikMany electrochemical devices are based on the fundamental process of ion migration and accumulation on surfaces. Complex interplay of molecular properties of ions and device dimensions control the entire process and define the overall dynamics of the system. Particularly, for ionic liquid-based electrolytes it is often not clear which property, and to what extent, contributes to the overall performance of the device. Herein we use X-ray photoelectron spectroscopy (XPS) while the device is under electrical bias. Such a procedure reveals localized electrical potential developments, through binding energy shifts of the atomic core levels, in a chemically specific fashion. Combining it with square-wave AC modulation, the information can also be extended to time domain, and we investigate devices configured as a coplanar capacitor, with an ionic liquid as the electrolyte, in macro-dimensions. Our analysis reveals that a nonlinear voltage profile across the device emerges from spatially non-uniform electrical double layer formation on electrode surfaces. Interestingly the coplanar capacitor has an extremely slow time response which is particularly controlled by IL film thickness. XPS measurements can capture the ion dynamics in the tens of seconds to microseconds range, and reveal that ionic motion is all over the device, including on metallic electrode regions. This behavior can only be attributed to motion in more than one dimension. The ion dynamics can also be faithfully simulated by using a modified PNP equation, taking into account steric effects, and device dimensions. XPS measurements on two devices with different dimensions corroborated and validated the simulation results. The present results propose a new experimental approach and provide new insights into the dynamics of ions across electrochemical devices.Item Open Access Temperature dependence of the first-order Raman scattering in GaS layered crystals(Pergamon Press, 2000) Gasanly, N. M.; Aydınlı, A.; Özkan, H.; Kocabaş, C.The temperature dependence (15-293 K) of the six Raman-active mode frequencies and linewidths in gallium sulfide has been measured in the frequency range from 15 to 380 cm-1. We observed softening and broadening of the optical phonon lines with increasing temperature. Comparison between the experimental data and theories of the shift and broadening of the interlayer and intralayer phonon lines during the heating of the crystal showed that the experimental dependencies can be explained by the contributions from thermal expansion and lattice anharmonicity. The pure-temperature contribution (phonon-phonon coupling) is due to three- and four-phonon processes.Item Open Access Temperature-dependent Raman scattering spectra of ε-GaSe layered crystal(Elsevier Science, 2002) Gasanly, N. M.; Aydnl, A.; Özkan, H.; Kocabaş, C.The temperature dependencies (15-300 K) of seven Raman-active mode frequencies and linewidths in layered gallium selenide have been measured in the frequency range from 10 to 320 cm-1. We observed softening and broadening of the optical phonon lines with increasing temperature. Comparison between the experimental data and theories of the shift and broadening of the intralayer phonon lines during heating of the crystal showed that the experimental dependencies can be explained by the contributions from thermal expansion, lattice anharmonicity and crystal disorder. The pure-temperature contribution (phonon-phonon coupling) is due to three-phonon processes. Moreover, it was established that the effect of crystal disorder on the linewidth broadening of TO mode is stronger than that of LO mode.