Tootoonchian, PedramKwiczak-Yiğitbaşı, JoannaTurab Ali Khan, MuhammadChalil Oglou, RamadanHolló, G.Karadaş, FerdiLagzi, I.Baytekin, Bilge2024-03-182024-03-182023-08-250947-6539https://hdl.handle.net/11693/114879Liesegang patterns that develop as a result of reaction-diffusion can simultaneously form products with slightly different sizes spatially separated in a single medium. We show here a reaction-diffusion method using a dormant reagent (citrate) for developing Liesegang patterns of cobalt hexacyanoferrate Prussian Blue analog (PBA) particle libraries. This method slows the precipitation reaction and produces different-sized particles in a gel medium at different locations. The gel-embedded particles are still catalytically active. Finally, the applicability of the new method to other PBAs and 2D systems is presented. The method proves promising for obtaining similar inorganic framework libraries with catalytic abilities. © 2023 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.EnglishLiesegang phenomenonParticle size libraryPeriodic patternsPolyacrylamide gelsPrussian Blue analoguesArticle10.1002/chem.2023012611521-3765