Shah, H. U.Wang, F.Toufiq, A. M.Khattak, A. M.Iqbal, A.Ghazi, Z. A.Ali, S.Li, X.Wang, Z.2018-04-122018-04-122016http://hdl.handle.net/11693/36642Single-crystalline Mn3O4 square-shaped nanostructures have been successfully synthesized by hydrothermal method without using any surfactant. The as-prepared products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), Transmission electron microscopy (TEM) and High Resolution transmission electron microscopy (HRTEM). To assess the potential properties of nanostructures, galvanostatic charging-discharging and cyclic voltammetry measurements were performed for their use in supercapacitors. The Mn3O4 nanoarchitectures used as supercapacitor electrode in 1mol L-1 KOH electrolyte have a specific capacitance value of 355.5 F g-1 at a low current density of 0.35 A.g-1. The device still retain 85.08% of its initial capacitance afterwards 2000 cycles at a current density of 5 A.g-1. The as-synthesized Mn3O4 nanostructures exhibited a good rate capability and stability for electrochemical properties. These results indicate their potential application as electrode material for high performance supercapacitor in basic medium.EnglishElectrochemical propertiesHydrothermal methodOptical propertiesSupercapacitanceTransition metal oxidesElectrochemical properties of single-crystalline Mn3O4 nanostructures and their capacitive performance in basic electrolyteArticle10.20964/2016.10.411452-3981