Turan, I. S.Akkaya, E. U.2016-02-082016-02-0820141523-7060http://hdl.handle.net/11693/26300An enhanced chemiluminescence signal is obtained when electronically triggered dioxetane cleavage is initiated by fluoride-mediated deprotection of the silyl-protecting group, followed by self-immolation via 1,4-quinone−methide rearrangement. The reaction takes place even when the probe is trapped within a PMMA layer on top of a glass plate. In that arrangement, fluoride in aqueous solutions can be detected selectively at low micromolar concentrations.EnglishArticle10.1021/ol50034121523-7052