Browsing by Subject "Tracer"

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    Sorption of phenol and radioactive cesium onto surfactant modified insolubilized humic acid
    (2010) Celebi, O.; Erten, H. N.
    In this study, the sorption behavior of two important contaminants, phenol and radioactive cesium (137Cs), onto surfactant modified insolubilized humic acid (SMIA) were investigated as a function of time, sorbate concentration utilizing the radiotracer method and UV-Vis spectroscopy. Phenol sorption process was well described by both Freundlich and Tempkin type isotherms, and cesium sorption was described by Freundlich and Dubinin-Radushkevich isotherms. It was found that SMIA adsorbs both cations and phenolic substances. Kinetic studies indicated that adsorption behavior of phenol obey the pseudo second order rate law. FTIR spectroscopic technique was used to understand the structural changes during modification process with surfactants.
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    Sorption studies of Cs+, Ba2+, and Co2+ ions on bentonite using radiotracer, ToF-SIMS, and XRD techniques
    (De Gruyter Oldenbourg, 2001) Shahwan, T.; Erten H. N.
    The sorption behaviour of Cs+, Ba2+, and Co2+ ions on bentonite were investigated using the radiotracer method, Time of Flight-Secondary Ion Mass Spectroscopy (ToF-SIMS), and X-Ray Diffraction (XRD). The sorption of Cs+ and Ba2+ were exothermic while sorption of Co2+ was endothermic. The sorption data were well described by Freundlich and Dubinin-Radushkevich isotherms. According to ToF-SIMS results Na+ and Mg2+ were the primary exchanging ions in bentonite. The XRD spectra showed that no structural changes were associated with the sorption of Cs+ and Co2+, and BaCO3 precipitate was formed upon the sorption of Ba2+ on bentonite.
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    Temperature effects in barium sorption on natural kaolinite and chlorite-illite clays
    (Akademiai Kiado Rt., 2004) Shahwan, T.; Erten, H. N.
    The sorption of Ba2+ ion on natural kaolinite and chlorite-illite clays was investigated at different initial concentrations and temperatures using the radiotracer method. The sorption data were well described by Freundlich and Dubinin-Radushkevich isotherms. Ba2+ sorption on both clays showed an exothermic behavior with ΔH° (kJ/mol) values being -7 and -5 for sorption on kaolinite and chlorite illite mixed clay, respectively. The ΔG° values indicate that the sorption was spontaneous with sorption energies corresponding to ion-exchange type sorption. X-ray diffraction studies showed that no significant change in the matrix of the clays occurred upon Ba2+ sorption.
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    Thermodynamic parameters of Cs+ sorption on natural clays
    (Akademiai Kiado Rt., 2002) Shahwan, T.; Erten, H. N.
    The sorption behavior of Cs+ on kaolinite, chlorite-illite, and bentonite clays as a function of time, cation concentration, and temperature was studied using the radiotracer method. Sorption data were well represented by Freundlich and Dubinin-Radushkevich type isotherms. Bentonite was found to have the highest sorption capacity and the highest exchange affinity to Cs+. In all three cases Cs+ sorption was found to be exothermic with ΔH° (kJ/mol) -13, -8, -19 and ΔS° (J/mol·K) -15, 31, and -3 for kaolinite, chlorite-illite, and bentonite, respectively. Negative ΔG° values were obtained in all cases, indicating the spontaneity of sorption. The magnitudes of ΔG° suggest that ion exchange is the primary sorption mechanism.
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    Uptake of Ba2+ ions by natural bentonite and CaCO3: a radiotracer, EDXRF and PXRD study
    (Akademiai Kiado Rt., 2002) Shahwan, T.; Atesin, A. C.; Erten, H. N.; Zararsiz, A.
    Ba2+ uptake by natural bentonite, CaCO3 in addition to a number of bentonite-CaCO3 mixtures with variable compositions as a function of pH and Ba2+ concentration was studied. Radiotracer method, EDXRF, and PXRD were used. The results of radiotracer experiments showed that the uptake of Ba2+ by CaCO3 was larger than its uptake by natural bentonite samples, particularly at low initial concentrations of Ba2+ and higher pH values. This finding was supported by the EDXRF results, According to the sorption data, the apparent ΔG° values of sorption were in the range -9±1 to -13±3 kJ/mol. The PXRD studies revealed the formation of BaCO3 upon sorption of Ba2+ on pure CaCO3 and on some of the bentonite-CaCO3 mixtures.
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    Vertical and horizontal water penetration velocity modeling in nonhomogenous soil using fast multi-output relevance vector regression
    (Mary Ann Liebert, Inc. Publishers, 2023-03) Vaheddost, B.; Arashloo, Shervin Rahimzadeh; Safari, MJS.
    A joint determination of horizontal and vertical movement of water through porous medium is addressed in this study through fast multi-output relevance vector regression (FMRVR). To do this, an experimental data set conducted in a sand box with 300 × 300 × 150 mm dimensions made of Plexiglas is used. A random mixture of sand having size of 0.5–1 mm is used to simulate the porous medium. Within the experiments, 2, 3, 7, and 12 cm walls are used together with different injection locations as 130.7, 91.3, and 51.8 mm measured from the cutoff wall at the upstream. Then, the Cartesian coordinated of the tracer, time interval, length of the wall in each setup, and two dummy variables for determination of the initial point are considered as independent variables for joint estimation of horizontal and vertical velocity of water movement in the porous medium. Alternatively, the multi-linear regression, random forest, and the support vector regression approaches are used to alternate the results obtained by the FMRVR method. It was concluded that the FMRVR outperforms the other models, while the uncertainty in estimation of horizontal penetration is larger than the vertical one.