Browsing by Subject "Fresh water"
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Item Open Access Correlations in metal release profiles following sorption by Lemna minor(Taylor and Francis Inc., 2016) Tunca, E. Ü.; Ölmez, T.T.; Özkan, A. D.; Altındağ, A.; Tunca, E.; Tekinay, T.ABSTRACT: Following the rapid uptake of contaminants in the first few hours of exposure, plants typically attempt to cope with the toxic burden by releasing part of the sorbed material back into the environment. The present study investigates the general trends in the release profiles of different metal(loid)s in the aquatic macrophyte Lemna minor and details the correlations that exist between the release of metal(loid) species. Water samples with distinct contamination profiles were taken from Nilüfer River (Bursa, Turkey), Yeniçağa Lake (Bolu, Turkey), and Beyşehir Lake (Konya, Turkey) and used for release studies; 36 samples were tested in total. Accumulation and release profiles were monitored over five days for 11 metals and a metalloid (208Pb, 111Cd, 52Cr,53Cr,60Ni,63Cu,65Cu,75As,55Mn, 137Ba, 27Al, 57Fe, 66Zn,68Zn) and correlation, cluster and principal component analyses were employed to determine the factors that affect the release of these elements. Release profiles of the tested metal(loid)s were largely observed to be distinct; however, strong correlations have been observed between certain metal pairs (Cr/Ni, Cr/Cu, Zn/Ni) and principal component analysis was able to separate the metal(loid)s into three well-resolved groups based on their release.Item Open Access Toxicity of lanthanum oxide (La2O3) nanoparticles in aquatic environments(Royal Society of Chemistry, 2015) Balusamy, B.; Taştan, B. E.; Ergen, S. F.; Uyar, Tamer; Tekinay, T.This study demonstrates the acute toxicity of lanthanum oxide nanoparticles (La2O3 NP) on two sentinel aquatic species, fresh-water microalgae Chlorella sp. and the crustacean Daphnia magna. The morphology, size and charge of the nanoparticles were systematically studied. The algal growth inhibition assay confirmed absence of toxic effects of La2O3 NP on Chlorella sp., even at higher concentration (1000 mg L-1) after 72 h exposure. Similarly, no significant toxic effects were observed on D. magna at concentrations of 250 mg L-1 or less, and considerable toxic effects were noted in higher concentrations (effective concentration [EC50] 500 mg L-1; lethal dose [LD50] 1000 mg L-1). In addition, attachment of La2O3 NP on aquatic species was demonstrated using microscopy analysis. This study proved to be beneficial in understanding acute toxicity in order to provide environmental protection as part of risk assessment strategies.