Molecular switch based on a cucurbit[6]uril containing bistable [3]rotaxane

Date
2007
Authors
Tuncel, D.
Özsar, Ö.
Tiftik, H. B.
Salih, B.
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Source Title
Chemical Communications
Print ISSN
1359-7345
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Volume
Issue
13
Pages
1369 - 1371
Language
English
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Abstract

A bistable CB6-based [3]rotaxane with two recognition sites has been prepared very efficiently in a high yield synthesis through CB6 catalyzed 1,3-dipolar cycloaddition; this rotaxane behaves as a reversible molecular switch and exhibits conformational changes caused by the movement of rings under base, acid and heat stimuli from one location to the other. © The Royal Society of Chemistry.

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