Gold nanoparticle/polymer nanofibrous composites by laser ablation and electrospinning
Deniz, A. E.
Vural, H. A.
Deniz, A. E., Vural, H. A., Ortaç, B., & Uyar, T. (2011). Gold nanoparticle/polymer nanofibrous composites by laser ablation and electrospinning. Materials Letters, 65(19), 2941-2943.
Please cite this item using this persistent URLhttp://hdl.handle.net/11693/12123
Poly(vinylpyrolidone) (PVP) nanofibers incorporating gold nanoparticles (Au-NPs) were produced in combination with laser ablation and electrospinning techniques. The Au-NPs were directly synthesized in PVP solution by laser ablation and then, the electrospinning of PVP/Au-NPs solution was carried out for obtaining nanofibrous composites. The presence of Au-NPs in the PVP nanofibers was confirmed by SEM, TEM and EDX analyses. The SEM imaging elucidated that the electrospun PVP/Au-NPs nanofibers were bead-free having average fiber diameter of 810 ± 480 nm. The TEM imaging indicated that the Au-NPs were in spherical shape having diameters in the range of 5 to 20 nm and the Au-NPs were more or less dispersed homogeneously in the PVP nanofiber matrix. The FTIR study suggested the presence of molecular interactions between PVP matrix and the Au-NPs in the nanofibrous composites. The UV–Vis measurement confirmed the enhancement of the optical properties of the PVP/Au-NPs nanofibers in the solid state due to the surface plasma resonance effect of Au-NPs.